7. Rank the strength of the following nucleophiles, in a solution of ethanol, in order of weakest to strongest. (3) weak CH3SH Strons CH30 weak CH3OH ČHĄS II II IV
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I had written those notes above the nucleophiles, so I am unsure if they are correct.
The species that contains a lone pair of electrons or negative charge known as a nucleophile. A nucleophile reacts with an electrophile.
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- Explain how and why rearrangements occurduring Friedel-Crafts alkylation reactions formingmore than 1 product. Also illustrate therearrangement reaction from the aboveexample.Arrange the following according to INCREASING reactivity towards E2: 1st ( least reactive)? 2nd? 3rd? 4th (most reactive)?3) Explain how and why the reaction below results in the observed regiochemistryand/or stereochemistry.
- the following reaction mechanism contains mistakes. which of the following statements correctly describes the curved arrows consistent with the reaction?Which would you think would be a strongerinteraction and why: an interaction between a sodium ion and thepartial negative charge on the oxygen in ethanol (CH3CH2OH), orthe interaction between two ethanol molecules?what is a possible mechanism for the following reaction ??
- Rank the following species from best nucleophile to poorest nucleophile in an aqueous solution:Explain the following reaction with a mechanism.Alkyl diazonium salts (shown below) are considered "super" leaving groups; a consequence of this is that they tend to be contact explosives What quailities make alkyl diazonium salts such excellent leaving groups?
- Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- Rate = k [CH3CH2Br][CH3COO-] Which mechanism would best fit the data?List the following in increasing order of nucleophilic strength. CH3COO-, H2O, CH3O-, OH-, CH3CH20-Identify which substitution mechanism best fits the following statement: The reaction proceeds through a concerted mechanism. A) SN1 B) SN2