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7.4 The following monomer reactivity ratios were determined for the binary copoly- merization of ferrocenylmethyl acrylate (FMA) with styrene (STY), methyl acrylate (MA), and vinyl acetate (VA) [C. U. Pittman, r., Macromolecules, 4, 298 (1971)]: M1 M2 r2 FMA STY 0.020 2.3 FMA МА 0.14. 4.4 FMA VA 1.4 0.46 (a) Which of the above comonomer pairs could lead to azeotropic copolymerization ? (b) Is styrene more reactive or less reactive than FMA toward the FMA radical ?

7.4 The following monomer reactivity ratios were determined for the binary copoly- merization of ferrocenylmethyl acrylate (FMA) with styrene (STY), methyl acrylate (MA), and vinyl acetate (VA) [C. U. Pittman, r., Macromolecules, 4, 298 (1971)]: M1 M2 r2 FMA STY 0.020 2.3 FMA МА 0.14. 4.4 FMA VA 1.4 0.46 (a) Which of the above comonomer pairs could lead to azeotropic copolymerization ? (b) Is styrene more reactive or less reactive than FMA toward the FMA radical ?

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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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7.4 The following monomer reactivity ratios were determined for the binary copoly- merization of ferrocenylmethyl acrylate (FMA) with styrene (STY), methyl acrylate (MA), and vinyl acetate (VA) [C. U. Pittman, Jr., Macromolecules, 4, 298 (1971)] : M1 M2 r2 FMA STY 0.020 2.3 FMA MA 0.14. 4.4 FMA VA 1.4 0.46 (a) Which of the above comonomer pairs could lead to azeotropic copolymerization ? (b) Is styrene more reactive or less reactive than FMA toward the FMA radical ?
Transcribed Image Text:7.4 The following monomer reactivity ratios were determined for the binary copoly- merization of ferrocenylmethyl acrylate (FMA) with styrene (STY), methyl acrylate (MA), and vinyl acetate (VA) [C. U. Pittman, Jr., Macromolecules, 4, 298 (1971)] : M1 M2 r2 FMA STY 0.020 2.3 FMA MA 0.14. 4.4 FMA VA 1.4 0.46 (a) Which of the above comonomer pairs could lead to azeotropic copolymerization ? (b) Is styrene more reactive or less reactive than FMA toward the FMA radical ?
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