7.6 In aqueous solution, boric acid behaves as a weak acid (pK, = 9.1) and the following equilibrium is established: B(OH)3(aq) + 2H,O(1) = [B(OH),]¯(aq) + [H;O]* (aq) (a) Draw the structures of B(OH)3 and [B(OH)4]¯. (b) How would you classify the acidic behaviour of B(OH);? (c) The formula of boric acid may also be written as H;BO3; compare the acidic behaviour of this acid with that of H3PO3.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter5: Alkenes: Bonding, Nomenclature, And Properties
Section: Chapter Questions
Problem 5.31P
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7.6 In aqueous solution, boric acid behaves as a weak acid
(pK, = 9.1) and the following equilibrium is
established:
B(OH)3(aq) + 2H,O(1)
= [B(OH),]¯(aq) + [H,O]*(aq)
(a) Draw the structures of B(OH); and [B(OH)4]¯.
(b) How would you classify the acidic behaviour of
B(OH);? (c) The formula of boric acid may also be
written as H;BO;; compare the acidic behaviour of
this acid with that of H;PO3.
Transcribed Image Text:7.6 In aqueous solution, boric acid behaves as a weak acid (pK, = 9.1) and the following equilibrium is established: B(OH)3(aq) + 2H,O(1) = [B(OH),]¯(aq) + [H,O]*(aq) (a) Draw the structures of B(OH); and [B(OH)4]¯. (b) How would you classify the acidic behaviour of B(OH);? (c) The formula of boric acid may also be written as H;BO;; compare the acidic behaviour of this acid with that of H;PO3.
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