8. Thallium (1) is oxidized by cerium (IV) as follows: TI+ + 2 Ce+ → T1³+ + 20e³+ The elementary steps are as follows: 1. Ce4+ + Mn²+ → Ce³+ + Mn³+ Ce4+ + Mn³+ → Ce³+ + Mn4+ 2. 3. TI+ + Mn4+ → T1³+ + Mn²+ a) Add all reactants and products and obtain the overall reaction. b) Identify the catalyst and intermediate. c) Determine which is the rate determining step if the rate law for the reaction is Rate = k(Ce4+][ Mn²+]

8. Thallium (1) is oxidized by cerium (IV) as follows: TI+ + 2 Ce+ → T1³+ + 20e³+ The elementary steps are as follows: 1. Ce4+ + Mn²+ → Ce³+ + Mn³+ Ce4+ + Mn³+ → Ce³+ + Mn4+ 2. 3. TI+ + Mn4+ → T1³+ + Mn²+ a) Add all reactants and products and obtain the overall reaction. b) Identify the catalyst and intermediate. c) Determine which is the rate determining step if the rate law for the reaction is Rate = k(Ce4+][ Mn²+]

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 93AE: At 620. K butadiene dimerizes at a moderate rate. The following data were obtained in an experiment...

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