9. At 80°C, Kc = 1.87 10-3 for the following reaction. PH3BCl3(s) PH3(g) + BCl3(g) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel and decomposes until equilibrium is reached. [PH3] _____M [BCl3] _____M (b) If the flask has a volume of 0.700 L, what is the minimum mass of PH3BCl3(s) that must be added to the flask in order to achieve equilibrium? _____g

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
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Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.53P
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9. At 80°C, Kc = 1.87  10-3 for the following reaction.

PH3BCl3(s)  PH3(g) + BCl3(g)
(a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel and decomposes until equilibrium is reached.
[PH3]
_____M
[BCl3]
 _____M

(b) If the flask has a volume of 0.700 L, what is the minimum mass of PH3BCl3(s) that must be added to the flask in order to achieve equilibrium?
 _____g
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