9. Infrared spectrum and microwave spectrum of a diatomic molecule (50 words max): (i) What model can be used to describe the infrared spectrum of a diatomic molecule? State both assumptions and limitations of the model. (ii) In the experiment, the microwave spectrum of a diatomic molecule consists of a series of lines but their separation is not exactly constant (as predicted by the model). Explain why.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.9E
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Quantum mechanics
 
 
 
9. Infrared spectrum and microwave spectrum of a diatomic
molecule (50 words max):
(i) What model can be used to describe the infrared
spectrum of a diatomic molecule?
State both assumptions and limitations of the model.
(ii) In the experiment, the microwave spectrum of a diatomic molecule consists of a series of
lines but their separation is not exactly constant (as predicted by the model). Explain why.
Transcribed Image Text:9. Infrared spectrum and microwave spectrum of a diatomic molecule (50 words max): (i) What model can be used to describe the infrared spectrum of a diatomic molecule? State both assumptions and limitations of the model. (ii) In the experiment, the microwave spectrum of a diatomic molecule consists of a series of lines but their separation is not exactly constant (as predicted by the model). Explain why.
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