A 0.125 M solution of Mn(NO3)2 is saturated with H2S ([H2S]=0.10 M). At what pH does MnS begin to precipitate?  MnS(s) ⇌ Mn2+(aq) + S2−(aq) Ksp = 4.3 × 10−22 H2S(aq) + 2H2O(l) ⇌ 2H3O+(aq) + S2−(aq) K =

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter14: Chemical Equilibrium
Section: Chapter Questions
Problem 14.79QE
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A 0.125 M solution of Mn(NO3)2 is saturated with H2S ([H2S]=0.10 M). At what pH does MnS begin to precipitate? 

MnS(s) ⇌ Mn2+(aq) + S2−(aq) Ksp = 4.3 × 10−22 H2S(aq) + 2H2O(l) ⇌ 2H3O+(aq) + S2−(aq) K = 1.0 × 10−26

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