A 0.3045 g of CaCO3 primary standard was dissolved using concentrated HCl, evaporated to incipient dryness, and quantitatively transferred to a 250 mL volumetric flask and diluted to mark. A 10 mL of aliquot was then transferred to an Erlenmeyer flask, together with 5mL buffer and 5 drops of EBT indicator, and was used to standardize the EDTA titrant. The solution turned blue after the addition of 24.10 mL of EDTA. A blank correction was made and was determined to be 0.4 mL.    [Analysis] A 30 mL unknown water sample was treated with 37.6 mL of EDTA. A blank correction was made and was determined to be 0.4 mL. What is the concentration of CaCO3 of the unknown water sample in ppm? (MW CaCO3 = 100.0869 g/mol)?

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter9: Complexometric And Precipitation Titrations
Section: Chapter Questions
Problem 17P
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[Standardization]

A 0.3045 g of CaCO3 primary standard was dissolved using concentrated HCl, evaporated to incipient dryness, and quantitatively transferred to a 250 mL volumetric flask and diluted to mark. A 10 mL of aliquot was then transferred to an Erlenmeyer flask, together with 5mL buffer and 5 drops of EBT indicator, and was used to standardize the EDTA titrant. The solution turned blue after the addition of 24.10 mL of EDTA. A blank correction was made and was determined to be 0.4 mL. 

 

[Analysis]

A 30 mL unknown water sample was treated with 37.6 mL of EDTA. A blank correction was made and was determined to be 0.4 mL. What is the concentration of CaCO3 of the unknown water sample in ppm? (MW CaCO3 = 100.0869 g/mol)?

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