A 50.00-mL aliquot of solution containing 0.358 of MgSO4 (FM 120.37) in 0.500 L required 38.08 mL of EDTA solution for titration. How many milligrams of CaCO3 (FM 100.09) will react with 1.00 mL of this EDTA solution?
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A 50.00-mL aliquot of solution containing 0.358 of MgSO4 (FM 120.37) in 0.500 L required 38.08 mL of EDTA solution for titration. How many milligrams of CaCO3 (FM 100.09) will react with 1.00 mL of this EDTA solution?
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- The accompanying data (1.00-cm cells) were obtained for the spectrophotometric titration 10.00 mL of Pd(II) with 2.44 10-4 M Nitroso R(O. W Rollins and M. M. Oldham, Anal. chem .,1971, 43, 262, DOI: 10.1021/ac60297a026). Calculate the concentration of the Pd(II) solution, given that the ligand-to-cation ratio in the colored product is 2:1A50.0 mL aliquot of solution contairing 0.450 g of MgSO4 [FM 120.27) in 0.500 L required 376 mL of EDTA solution for titration. How many miligrams of CaCO3 (FM 106.09) will react with 100 mL of this EDTA solution?A 30-mL portion of a solution containing Ca2+ and Mg2+ was titrated with 28.19 mL of 0.213 M EDTA at pH 10. Another 30-mL aliquot of the same Ca-Mg mixture was treated with NaOH to make the solution strongly alkaline and precipitate Mg(OH)2. This solution was then titrated with the same EDTA solution. What would be the required EDTA volume (in mL) to reach the endpoint of the second aliquot if it was found that there was 0.061 M of Mg2+ in the sample?
- a. A deepwell water sample of 100 mL was titrated with 0.010 M EDTA at pH 10 ( with Mg-EDTA pH 10 buffer reagent) and consumed 31 mL. Calculate the Total Hardness of the water sample as mg CaCO3. b. A deepwell water sample of 100 mL was titrated with 0.010 M EDTA at pH 12 and consumed 31 mL. Calculate the Calcium content of the water sample in mg/L.A 5.00 mL tap water sample was measured out with a volumetric pipette, and added to a 25 mL Erlenmeyer flask. It was then titrated with a 0.0100 M Na2EDTA.2H2O solution, and found to take 0.635 mL of the EDTA solution to reach the blue endpoint.A 5.00 mL sample that contains the borate ion {B4O5(OH)42-} at 35oCwas transferred to an Erlenmeyer flask and diluted with water to ~25 mL. This solution was titrated with 20.9 mL of 0.21 M HCl to the bromocresol green endpoint. What is the Ksp for the borax? Report your Ksp value to 3 decimal places.
- Calculate the PCa vs. EDTA titration curve for 50.0 mL of 0.0060 M Ca2+ being titrated with 0.0150 M EDTA in a solution buffered to a constant pH of 10.00. After the addition of 0.00 mL After the addition of 5.00 mL After the addition of 26.00 mLA deepwell water sample of 100 mL was titrated with 0.010 M EDTA at pH 12 and consumed 31 mL. Calculate the Calcium content of the water sample in mg/L.A 50.00 ml aliquot of a solution containing Ca2+ and Mg2+ was buffered at pH 10 and titrated with 0.0418 M EDTA. The endpoint volume was 44.36 ml. A second aliquot of the same mixture was made strongly basic by the addition of NaOH – this causes the Mg2+ to precipitate as Mg(OH)2. The solution was then titrated with the 0.0418 M EDTA and the endpoint volume was found to be 30.02 ml. Calculate the molar concentration of Mg.
- A solution containing 1.263 g of unknown potassium compound was dissolved in water and treated with excess sodium tetraphenylborate, Na1B1C6H524 solution to precipitate 1.003 g of insoluble K1B1C6H524 (FM 358.33). Find wt% K in the unknown.A 25.00 mL sample containing Fe3+ was treated with 10.00 mL of 0.03676 M EDTA to complex all the Fe3+ and leave excess EDTA in solution. The excess EDTA was then back-titrated, requiring 2.37 mL of 0.04615 M Mg2+. What was the concentration of Fe3+ in the original solution in ppm Fe3+?A sample of anhydrous NaHCO3 (FM = 84.007) is suspected to be contaminated with eitherNaOH (FM = 39.997) or Na2CO3 (FM = 105.989). To verify the suspicion, a 0.7483 g sample was dissolved to prepare a 50.00 mL solution, and a 10.00 mL aliquot was taken to prepare a 100 mL solution, where 25.00 mL was analyzed using double flask method. If the sample requires 0.45 mL of standard 0.0125 N HCl to reach the phenolphthalein endpoint and 35.95 mL to reach the bromcresol green endpoint, calculate the percentage composition (in %w/w) of all the basic components in the sample.
