A 185.0 mL sample of 1.200M Pb(NO3)2 is mixed with 139.50 mL of 1.500 M NaCl, and the PbCl2 precipitate is filtered from the solution. Then 200.0 mL of 3.000 M NaBr is added to the remaining solution, and the PbBr2 precipitate is also collected and dried. What is the mass (in grams) of the PbBr2 precipitate, assuming the yield in each precipitation step is 100%?
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A: The balanced reaction is as follows: Pb(NO3)2(aq)+Na2SO4(aq)→PbSO4(s)+2NaNO3(aq)
Q: A 1.22 g sample of impure lead nitrate was dissolved in 40.0 mL of distilled water and analyzed by…
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- To determine the fluoride content in an aqueous and chloride-containing preparation of ammonium fluoride, the following analysis was performed. 105.2 mg of the preparation was dissolved in 100.0 mL of water. Then a 300 mL 40 mM lead chloride solution was added, whereby all fluoride ions were precipitated out of the solution in the form of the sparingly soluble salt PbClF (s). The precipitate was separated and washed at 15 degrees with a lead fluoride chloride saturated solution and dried at 130 degrees. The precipitate weighed 651.3 mg. a) Calculate the fluoride content (as % by weight F) in the preparation.b) Determine the purity of the ammonium fluoride preparationA 185 mL sample of 1.20 M Pb(NO₃)₂ is mixed with 61.5 mL of 1.50 M NaCl, and the PbCl₂ precipitate is filtered from the solution. Then 200 mL of 3.00 M NaBr is added to the remaining solution, and the PbBr₂ precipitate is also collected and dried. What is the mass of the PbBr₂ precipitate, assuming the yield in each precipitation step is 100%?What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.
- Estimate the aqueous gram-solubility in g/L of mercury(I) chloride: Hg2Cl2(s) ↔ 2Hg+ (aq) + 2Cl– (aq), Ksp = 1.43×10–18 The molar mass of Hg2Cl2 is 472.06 g/mol.The hardness of water (hardness count) is usually expressed in parts per million (by mass) of CaCO3. What is the molar concentration of Ca2+ ions in a water sample with a hardness count of 175mg CaCO3il? How many milliliters of concentrated sulfuric acid, 94.0% (w/w), specific gravity of 1.831 are required to prepare 1 liter of a 0.100 M solution? The solubility-product constant for Ce(IO3)3 is 3.2x1010. What is the Ce3+ concentration in a solution prepared by mixing 50.0 ml of 0.0250 M Ce3.. with 50.00 ml of water?The maximum solid solubility of carbon in ferrite occurs at 0.022 wt% C and 727 ° C, the eutectoid composition is 0.76 wt% C, the maximum solid solubility of carbon in austenite occurs at 2.14 wt% C and 1147 ° C, and the cementite composition is 6.7 wt% C. For 2122 g of a 3.2134 wt% C steel at 726 ° C, what will be the mass of carbon present as part of a compound?(a) 67.9 g(b) 74.2 g(c) 58.7 g(d) 83.5 g
- Consider the reaction of Potassium Phosphate and Nickel (II) Bromide, where 15.00 ml of 0.7000M K3PO4 is mixed with 15.00ml of 0.2000M NiBr2 (and the final volume is 30.00 ml, that is there is no change in volume upon mixing). Your answer has to include all of the following: What is the limiting reagent? What is the identity and mass of precipitate formed? What is the concentration of the alkali metal that is a spectator ion? What is the concentration of the excess phosphate?The arsenic in a 1.010 g sample of a pesticide was converted to H3AsO4 by suitable treatment. The acid was then neutralized, and exactly 40.00 mL of 0.06222M AgNO3 was added to precipitate the arsenic quantitatively as Ag3AsO4. The excess Ag in the filtrate and in the washings from theprecipitate was titrated with 10.76 mL of 0.1000MKSCN; the reaction wasAg+ + SCN-→ AgSCN(s) Calculate the percent AsO3 in the sample.The amount of sulfate in a solid sample was determined by first dissolving 562.2 mg of sample in water, and then precipitating the sulfate by the addition of 25.00 mL of 0.022 96 M BaCl2. The precipitate was filtered from the solution and the remaining Ba2+ was titrated with 16.52 mL of 0.014 57 M EDTA. What was the mass percent of sulfate in the solid?
- 1.Calculate the normality of the solutions containing 5.267g/L K2Cr2O7 (the Cr is reduced to Cr3+).(FW=294.19 g/mol) 2.A and B react as follows: A + B 2C. The equilibrium constant is 5.0 x 106. If 0.40 mol of Aand 0.70 mol of B are mixed in 1L, what are the concentrations of A, B and C after reaction? 3. The following data is given at a certain temperature:(1) 2N2 (g) + O2 (g) 2N2O (g) K1 = 1.2 x 10-35(2) N2O4 (g) 2NO2 (g) K2 = 4.6 x 10-3(3) ½N2 (g) + O2 (g) NO2 (g) K3 = 4.1 x 10-9Calculate the molar equilibrium constant, K for the reaction:2N2O (g) + 3O2 (g) 2N2O4 (g)1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.The following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mL
