A 2.0-cmcm-diameter, 0.50-mmmm-thick spherical plastic shell holds carbon dioxide at 2.0 atm pressure and 25°C. CO2 molecules diffuse out of the shell into the surrounding air, where the carbon dioxide concentration is essentially zero. The diffusion coefficient of carbon dioxide in the plastic is 2.5x10-12 m2/s. a. What is the diffusion rate in molecules/s of carbon dioxide out of the shell? Express your answer in molecules per second. b. If the rate from part A is maintained, how long in hours will it take for the carbon dioxide pressure to decrease to 1.0 atm? The actual rate slows with time as the concentration difference decreases, but assuming a constant rate gives a reasonable estimate of how long the shell will contain the carbon dioxide. Express answer in hours.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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A 2.0-cmcm-diameter, 0.50-mmmm-thick
spherical plastic shell holds carbon dioxide
at 2.0 atm pressure and 25°C. CO2
molecules diffuse out of the shell into the
surrounding air, where the carbon dioxide
concentration is essentially zero. The
diffusion coefficient of carbon dioxide in the
plastic is 2.5x10-12 m2/s.
a. What is the diffusion rate in molecules/s
of carbon dioxide out of the shell? Express
your answer in molecules per second.
b. If the rate from part A is maintained, how
long in hours will it take for the carbon
dioxide pressure to decrease to 1.0 atm?
The actual rate slows with time as the
concentration difference decreases, but
assuming a constant rate gives a
reasonable estimate of how long the shell
will contain the carbon dioxide. Express
answer in hours.
Transcribed Image Text:A 2.0-cmcm-diameter, 0.50-mmmm-thick spherical plastic shell holds carbon dioxide at 2.0 atm pressure and 25°C. CO2 molecules diffuse out of the shell into the surrounding air, where the carbon dioxide concentration is essentially zero. The diffusion coefficient of carbon dioxide in the plastic is 2.5x10-12 m2/s. a. What is the diffusion rate in molecules/s of carbon dioxide out of the shell? Express your answer in molecules per second. b. If the rate from part A is maintained, how long in hours will it take for the carbon dioxide pressure to decrease to 1.0 atm? The actual rate slows with time as the concentration difference decreases, but assuming a constant rate gives a reasonable estimate of how long the shell will contain the carbon dioxide. Express answer in hours.
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