A 50.0ml sample of water containing both Ca+2 and Mg+2 is titrated with 16.54ml of 0.01104M EDTA in an ammonia buffer of pH 10. Another 50.0ml sample is treated with NaOH to precipitate the Mg(OH)2 and then titrated at pH 13 with 9.26ml of the same EDTA solution. Calculate the ppm each of CaCO3 and MgCO3 in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.35QAP
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A 50.0ml sample of water containing both Ca+2 and Mg+2 is titrated with 16.54ml of 0.01104M EDTA in an ammonia buffer of pH 10. Another 50.0ml sample is treated with NaOH to precipitate the Mg(OH)2 and then titrated at pH 13 with 9.26ml of the same EDTA solution. Calculate the ppm each of CaCO3 and MgCO3 in the sample.

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