A 60.0 mL sample of 1.0 M NaOH is mixed with 45.0 mL of 1.0 M H2SO4 in a large Styrofoam coffee cup; the cup is fitted with a lid through which passes a calibrated thermometer. The temperature of each solution before mixing is 25.9°C. After adding the NaOH solution to the coffee cup, the mixed solutions are stirred until reaction is complete. Assume that the density of the mixed solutions is 1.0 g/mL, that the specific heat of the mixed solutions is 4.18 J/(g •°C), and that no heat is lost to the surroundings. The AHrxn for the neutralization of NaOH with H2SO4 is -114 kJ/mol H2SO4. What is the maximum measured temperature in the Styrofoam cup? °C

A 60.0 mL sample of 1.0 M NaOH is mixed with 45.0 mL of 1.0 M H2SO4 in a large Styrofoam coffee cup; the cup is fitted with a lid through which passes a calibrated thermometer. The temperature of each solution before mixing is 25.9°C. After adding the NaOH solution to the coffee cup, the mixed solutions are stirred until reaction is complete. Assume that the density of the mixed solutions is 1.0 g/mL, that the specific heat of the mixed solutions is 4.18 J/(g •°C), and that no heat is lost to the surroundings. The AHrxn for the neutralization of NaOH with H2SO4 is -114 kJ/mol H2SO4. What is the maximum measured temperature in the Styrofoam cup? °C

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter7: Chemical Energy

Section: Chapter Questions

Problem 64E: Consider the reaction 2HCl(aq)+Ba(OH)2(aq)BaCl2(aq)+2H2O(l)H=118KJ Calculate the heat when 100.0 rnL...

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A student performing a calorimetry experiment combined 100.0 ml. of 0.50 M HCI and 100.0 ml. of 0.50 M NaOH in a StyrofoamTM cup calorimeter. Both solutions were initially at 20.0 C, but when the two were mixed, the temperature rose to 23.2 C (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 ml of 0.50 M NaOH. WIII the AT observed be greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCI and 100.0 ml. of 1.00 M NaOH. Will the T observed be greater than, less than, or equal to that in the first experiment, and why?
Benzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.
For the reaction BaCO3(s) BaO(s) + CO2(g), rG = +219.7 kJ/mol-rxn. Using this value and other data available in Appendix L, calculate the value of fG for BaCO3(s).
When 1.000 g of gaseous butane, C4H10, is burned at 25C and 1.00 atm pressure, H2O(l) and CO2(g) are formed with the evolution of 49.50 kJ of heat. a Calculate the molar enthalpy of formation of butane. (Use enthalpy of formation data for H2O and CO2.) b Gf of butane is 17.2 kJ/mol. What is G for the combustion of 1 mol butane? c From a and b, calculate S for the combustion of 1 mol butane.
The reaction enthalpy for oxidation of styrene, C8H8, has been measured by calorimetry. C8H8() + 10 O2(g) 8 CO2(g) + 4 H2O() rH = 4395.0 kJ/mol Use this value, along with the data from Table 4.2, to calculate the standard formation enthalpy of styrene, in kJ/mol. Table 4.2 Selected Standard Formation Enthalpies, fH, at 25C
What is the sign of the work when a refrigerator compresses a gas (the system) to a liquid during the refrigeration cycle?
Consider the reaction 2HCl(aq)+Ba(OH)2(aq)BaCl2(aq)+2H2O(l)H=118KJ Calculate the heat when 100.0 rnL of 0.500 M HCl is mixed with 300.0 mL of 0.100 M Ba(OH)2 Assuming that the temperature of both solutions was initially 25.0C and that the final mixture has a mass of 400.0 g and a specific heat capacity of 4.18 J/C g, calculate the final temperature of the mixture.
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
Identify the sign of the work when a fuel-oxygen mixture (the system) burns, propelling an automobile (part of the surroundings).

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