A₂ = A + A (k₁ and k-₁) A + B → P (K₂) i) Solve for dP/dt using a pre-equilibrium assumption ii) Solve for dP/dt using the steady state approximation. (you'll solve a quadratic equation) ii) Show, and clearly state in words, which assumptions make your answer for (ii) become the same as (i)

Chemical Principles in the Laboratory
11th Edition
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Chapter21: Rates Of Chemical Reactions, Ii. A Clock Reaction
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A₂ = A + A (k₁ and k_₁ )
A+B → P (K₂)
i) Solve for dP/dt using a pre-equilibrium assumption
ii) Solve for dP/dt using the steady state approximation. (you'll solve a quadratic equation)
ii) Show, and clearly state in words, which assumptions make your answer for (ii) become the
same as (i)
Transcribed Image Text:A₂ = A + A (k₁ and k_₁ ) A+B → P (K₂) i) Solve for dP/dt using a pre-equilibrium assumption ii) Solve for dP/dt using the steady state approximation. (you'll solve a quadratic equation) ii) Show, and clearly state in words, which assumptions make your answer for (ii) become the same as (i)
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