A battery harnesses a chemical reaction to extract energy in the form of useful electrical work. (a) A certain battery runs a toy truck and becomes par- tially discharged. In the process, it performs a total of 117.0 J of work on its immediate surroundings. It also gives off 3.0 J of heat, which the surroundings absorb. No other work or heat is exchanged with the sur- roundings. Compute q, w, and AU of the battery, making sure each quantity has the proper sign. (b) The same battery is now recharged exactly to its origi- nal condition. This requires 210.0 J of electrical work from an outside generator. Determine q for the battery in this process. Explain why q has the sign that it does.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
Section: Chapter Questions
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A battery harnesses a chemical reaction to extract energy
in the form of useful electrical work.
(a) A certain battery runs a toy truck and becomes par-
tially discharged. In the process, it performs a total of
117.0 J of work on its immediate surroundings. It also
gives off 3.0 J of heat, which the surroundings absorb.
No other work or heat is exchanged with the sur-
roundings. Compute q, w, and AU of the battery,
making sure each quantity has the proper sign.
(b) The same battery is now recharged exactly to its origi-
nal condition. This requires 210.0 J of electrical work
from an outside generator. Determine q for the battery
in this process. Explain why q has the sign that it does.
Transcribed Image Text:A battery harnesses a chemical reaction to extract energy in the form of useful electrical work. (a) A certain battery runs a toy truck and becomes par- tially discharged. In the process, it performs a total of 117.0 J of work on its immediate surroundings. It also gives off 3.0 J of heat, which the surroundings absorb. No other work or heat is exchanged with the sur- roundings. Compute q, w, and AU of the battery, making sure each quantity has the proper sign. (b) The same battery is now recharged exactly to its origi- nal condition. This requires 210.0 J of electrical work from an outside generator. Determine q for the battery in this process. Explain why q has the sign that it does.
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