A buffered solution of 0.0570 M Sbo* and 0.0200 M Cd²+ was prepared with a pH of 2.70 at 25 °C. Sbot + 2 H* + 3e¯= Sb(s) + H,0 Cd2+ + 2 e= Cd(s) Sbo+ = 0.208 V = -0.402 V E: Which ion is more easily reduced? Cd²+ O Sbot What is the concentration of SbOt at the potential when Cd²+ will begin to be deposited? [SbO*] = M Determine the potential at the cathode when the SbOt concentration is 0.0019 M? Ecathode V

Principles of Instrumental Analysis
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Chapter24: Coulometry
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Problem 24.5QAP: What cathode potential (versus SCE) would be required to lower the total Hg(II) concentration of the...
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A buffered solution of 0.0570 M Sbo* and 0.0200 M Cd²+ was prepared with a pH of 2.70 at 25 °C.
Sbot + 2 H* + 3e¯= Sb(s) + H,0
Cd2+ + 2 e= Cd(s)
Sbo+ = 0.208 V
= -0.402 V
E:
Which ion is more easily reduced?
Cd²+
O Sbot
What is the concentration of SbOt at the potential when Cd²+ will begin to be deposited?
[SbO*] =
M
Determine the potential at the cathode when the SbOt concentration is 0.0019 M?
Ecathode
V
Transcribed Image Text:A buffered solution of 0.0570 M Sbo* and 0.0200 M Cd²+ was prepared with a pH of 2.70 at 25 °C. Sbot + 2 H* + 3e¯= Sb(s) + H,0 Cd2+ + 2 e= Cd(s) Sbo+ = 0.208 V = -0.402 V E: Which ion is more easily reduced? Cd²+ O Sbot What is the concentration of SbOt at the potential when Cd²+ will begin to be deposited? [SbO*] = M Determine the potential at the cathode when the SbOt concentration is 0.0019 M? Ecathode V
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