(a) Calculate the theoretical lattice energy for the salt CaF2. (b) The hydration enthalpy of Ca²+ is –1592 kJ mol-1; the hydration enthalpy of F¯ is –497 kJ mol-. Calculate the enthalpy of precipitation of CaF2. (c) Ignoring entropy effects, use the results of your calculations to predict whether CaF; is soluble or insoluble. Can entropy effects generally safely be ignored in questions like this?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
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28. (a) Calculate the theoretical lattice energy for the salt CaF2. (b) The hydration
enthalpy of Ca²+ is –1592 kJ mol-; the hydration enthalpy of F is -497 kJ mol-.
Calculate the enthalpy of precipitation of CaF2. (c) Ignoring entropy effects, use the
results of your calculations to predict whether CaF, is soluble or insoluble. Can
entropy effects generally safely be ignored in questions like this?
Transcribed Image Text:28. (a) Calculate the theoretical lattice energy for the salt CaF2. (b) The hydration enthalpy of Ca²+ is –1592 kJ mol-; the hydration enthalpy of F is -497 kJ mol-. Calculate the enthalpy of precipitation of CaF2. (c) Ignoring entropy effects, use the results of your calculations to predict whether CaF, is soluble or insoluble. Can entropy effects generally safely be ignored in questions like this?
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