(a) Calculate the theoretical lattice energy for the salt CaF2. (b) The hydration enthalpy of Ca²+ is –1592 kJ mol-1; the hydration enthalpy of F¯ is –497 kJ mol-. Calculate the enthalpy of precipitation of CaF2. (c) Ignoring entropy effects, use the results of your calculations to predict whether CaF; is soluble or insoluble. Can entropy effects generally safely be ignored in questions like this?
(a) Calculate the theoretical lattice energy for the salt CaF2. (b) The hydration enthalpy of Ca²+ is –1592 kJ mol-1; the hydration enthalpy of F¯ is –497 kJ mol-. Calculate the enthalpy of precipitation of CaF2. (c) Ignoring entropy effects, use the results of your calculations to predict whether CaF; is soluble or insoluble. Can entropy effects generally safely be ignored in questions like this?
Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
Problem 13.5QAP
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