A clock reaction is commonly used to demonstrate principles of chemical kinetics. In a clock reaction, an initially colorless solution changes color at a precise time during the course of the reaction. One such clock reaction is based on a reaction between S2O82– and I–. The rate law was determined to be rate = k [ S2O82–] [I–]. The following mechanism has been proposed for the reaction. Predict whether the steps are fast or slow based on the overall rate law.
A clock reaction is commonly used to demonstrate principles of chemical kinetics. In a clock reaction, an initially colorless solution changes color at a precise time during the course of the reaction. One such clock reaction is based on a reaction between S2O82– and I–. The rate law was determined to be rate = k [ S2O82–] [I–]. The following mechanism has been proposed for the reaction. Predict whether the steps are fast or slow based on the overall rate law.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 84QRT: Many biochemical reactions are catalyzed by acids. A typical mechanism consistent with the...
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A clock reaction is commonly used to demonstrate principles of
S2O82–+ I– yield IS2O83– fast or slow
IS2O83– yield 2 SO42– + I+ fast or slow
I++ I– yield I2 fast or slow
I2+ I– yield I3– fast or slow
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