A galvanic cell is constructed with one compartment that contains a mercury electrode immersed in a 1 M aqueous solution of mercuric acetate Hg(CH3CO2)2Hg(CH3CO2)2 and one compartment that contains a strip of magnesium immersed in a 1 M aqueous solution of MgCl2MgC12. When the compartments are connected, a potential of 3.22 V is measured and the following half reactions occur: cathode: Hg (aq) + 2e → Hg(1) anode: Mg(s) Mg¹(aq) + 2e If the potential for the oxidation of Mg to Mg2 is 2.37 V under standard conditions, what is the standard electrode potential for the reaction that occurs at the anode?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter18: Electrochemistry
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Problem 159MP: A galvanic cell is based on the following half-reactions: In this cell, the copper compartment...
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A galvanic cell is constructed with one compartment that contains a mercury electrode immersed in a 1 M aqueous solution of mercuric acetate Hg(CH3CO2)2Hg(CH3CO2)2 and one compartment that contains a strip of magnesium immersed in a 1 M aqueous solution of MgCl2MgC12. When the compartments are connected, a potential of 3.22 V is measured and the following half reactions occur: cathode: Hg (aq) + 2e → Hg(1) anode: Mg(s) Mg¹(aq) + 2e If the potential for the oxidation of Mg to Mg2 is 2.37 V under standard conditions, what is the standard electrode potential for the reaction that occurs at the anode?
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