a) Given the Fischer projection for D-ribose below, draw the structure of 8-0-ibofuranose -OH -OH -OH CHUCH b) The molecule below is a flavonoid glycoside found in the medicinal plant Alphtonia xerocarpos ● On the structure, identify an anomeric carbon with an asterisk (") Identify a 3-glycosidic linkage with an arrow. 40 Draw the three main organic products obtained from treatment of this flavonoid glycoside with aqueous acid N) The flavonoid glycoside can mutarotate. With direct reference to the structure above, provide an explanation for this.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter25: Carbohydrates
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Problem 25.36P
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a) Given the Fischer projection for D-ribose below, draw the structure of 3-D-ribofuranose.
H₂
OH
OH
OH
CH₂OH
b) The molecule below is a flavonoid glycoside found in the medicinal plant Alphitonia xerocarpos
0
On the structure, identify an anomeric carbon with an asterisk (").
4)
Identify a-glycosidic linkage with an arrow.
NO
Draw the three main organic products obtained from treatment of this flavonoid glycoside with
aqueous acid.
W)
The flavonoid glycoside can mutarotate. With direct reference to the structure above, provide an
explanation for this.
H
H
Transcribed Image Text:a) Given the Fischer projection for D-ribose below, draw the structure of 3-D-ribofuranose. H₂ OH OH OH CH₂OH b) The molecule below is a flavonoid glycoside found in the medicinal plant Alphitonia xerocarpos 0 On the structure, identify an anomeric carbon with an asterisk ("). 4) Identify a-glycosidic linkage with an arrow. NO Draw the three main organic products obtained from treatment of this flavonoid glycoside with aqueous acid. W) The flavonoid glycoside can mutarotate. With direct reference to the structure above, provide an explanation for this. H H
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