A laboratory manager wants to prepare 500.00 mL of a buffer with a pH of 4.471 from equimolar solutions of CH3CO2H (Ka = 1.800e-5) and LiCH3CO2. What volume of the LiCH3CO2 solution would be required?
A laboratory manager wants to prepare 500.00 mL of a buffer with a pH of 4.471 from equimolar solutions of CH3CO2H (Ka = 1.800e-5) and LiCH3CO2. What volume of the LiCH3CO2 solution would be required?
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 34QAP: A buffer is prepared using the butyric acid/butyrate (HC4H7O2/C4H7O2)acid-base pair. The ratio of...
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A laboratory manager wants to prepare 500.00 mL of a buffer with a pH of 4.471 from equimolar solutions of CH3CO2H (Ka = 1.800e-5) and LiCH3CO2. What volume of the LiCH3CO2 solution would be required?
Key Concept: Buffers resist pH change and are prepared by mixing the conjugate acid and base together. The pH is determined from the Henderson-Hasselbach equation: pH = pKa + log([A−]/[HA]).
Solution: Since the molarities of the two solutions making the buffer are the same, the Henderson-Hasselbach equation can be written as: pH = pKa + log(V(A−)/V(HA)) where V(A−) = the volume of the conjugate base and V(HA) = the volume of the conjugate acid.
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