A mixture of 3 moles of NO and 4 moles of H2O is placed in a 5 L container and heated to 300 degrees C where the equilibrium 4NH3 (g) + 5O2 (g) ⇄ 4NO(g) + 6H2O(g) is established. At equilibrium, the NH3 , O2 , NO and H2O concentrations were 0.45, 0.5625, 0.15, and 0.125 moles/L, respectively. The volume of the container is then reduced from 5 L to 1 L. What is the equilibrium constant, Kc, after equilibrium is re-established at the reduced volume?

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
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Problem 7.81P
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A mixture of 3 moles of NO and 4 moles of H2O is placed in a 5 L container and heated to 300 degrees C where the equilibrium

4NH3 (g) + 5O2 (g) ⇄ 4NO(g) + 6H2O(g)

is established. At equilibrium, the NH3 , O2 , NO and H2O concentrations were 0.45, 0.5625, 0.15, and 0.125 moles/L, respectively. The volume of the container is then reduced from 5 L to 1 L. What is the equilibrium constant, Kc, after equilibrium is re-established at the reduced volume?

a) 6.43x10-9

b) 1.20x106

c) 7.62x10-5

d) 3.94x108

e) 8.36x10-7

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