A particle of spin 1/2 and mass m moves subject to the Hamiltonian: P² 1 1 1 P² = +/-mw²X² + +=mw²y² + + 1/mw²z². 2" 2m '2' P² 2m 2 2m Ho A disturbance given by W = Xo R₁ where o contains the Pauli matrices. Calculate the change in energy from the ground state to first order in the perturbation (don't forget the degeneracy introduced by the spin).

A particle of spin 1/2 and mass m moves subject to the Hamiltonian: P² 1 1 1 P² = +/-mw²X² + +=mw²y² + + 1/mw²z². 2" 2m '2' P² 2m 2 2m Ho A disturbance given by W = Xo R₁ where o contains the Pauli matrices. Calculate the change in energy from the ground state to first order in the perturbation (don't forget the degeneracy introduced by the spin).

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter18: Raman Spectroscopy

Section: Chapter Questions

Problem 18.5QAP

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