A sample of pyrolusite weighing 0.6000 g is dissolved in a solution containing 5.00 mL of 6.00 N H2SO4 and 0.900 g of H2C2O4 .2H2O. The excess oxalate then requires 24.00 mL of KMnO4 solution for titration. If each mL of the KMnO4 will oxidize the Fe(II) in 0.03058 g FeSO4 .7H2O, what is the oxidizing power of the sample in terms of MnO2

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.15QAP
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A sample of pyrolusite weighing 0.6000 g is dissolved in a solution

containing 5.00 mL of 6.00 N H2SO4 and 0.900 g of H2C2O4 .2H2O. The excess

oxalate then requires 24.00 mL of KMnO4 solution for titration. If each mL of the KMnO4 will oxidize the Fe(II) in 0.03058 g FeSO4 .7H2O, what is the oxidizing power of the sample in terms of MnO2?

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