(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H2C2O4.2H20 and dilute H2SO4 and after reduction has taken place (MnO2 + H2C2O4 + 2H+ Mn2+ + 2CO2 + 2H2O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMNO4 for titration? (b) If pure As2O3 were used instead

(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H2C2O4.2H20 and dilute H2SO4 and after reduction has taken place (MnO2 + H2C2O4 + 2H+ Mn2+ + 2CO2 + 2H2O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMNO4 for titration? (b) If pure As2O3 were used instead

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.15QAP

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(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000g is treated with 0.6000g of pure H2C2O4•2H2O and dilute H2SO4 and after reduction has taken place (MnO2 + H2C2O4 + 2H+→ Mn2++ 2CO2 + 2H2O), the excess oxalic acid requires 26.26ml of 0.1000N KMnO4 for titration? (b) If pure As2O3 were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?
Silver(ag) is obtained in much of the same manner as gold using NaCN solution and O2. Describe with appropriate equation the extraction of Ag from argentite Ag2S. The products are SO2 and Ag(CN)2 which are reduced with ZN?
A 1.1324 g sample of magnetite ore was dissolved in concentrated HCl to give a solution that contained a mixture of Fe2+ and Fe3+. Nitric acid was added and the solution was boiled for a few minutes, which converted all of the iron to Fe3+. The Fe3+ was then precipitated as Fe2O3*xH2O by addition of NH3. After filtration and washing, the residue was ignited at a high temp to give 0.5394 g of pure Fe2O3. What is the percent Fe and the percent Fe3O4 in the sample?
Cite the overall reaction for the extraction of (a) Fe, (b) Al, and (c) Mg from their corresponding metal oxides when coupled with the oxidation of C (s) to CO (g). Which of these metals can be extracted from its oxide at 1800 °C?
Silver is obtained in much of the same manner as gold using NACN solution and O2. Describe with appropriate equation the extraction of Ag from Argentite Ag2S. The products are SO2 and Af(CN) -2 which are reduced with Zn
Pyrolusite (MnO2) is dissolved in hydrochloric acid:MnO2 + HCl → MnCl2 + H2O + Cl2The chloride was passed into potassium iodide solution where it liberated iodine:Cl2 + KI → KCl + I2The iodine liberated was estimated by adding sodium thiosulfate, the reaction beingI2 + Na2S2O3 → NaI + Na2S4O6If 5.6 g of crystallized sodium thiosulfate, Na2S2O3 5H2O ,were used up, how many grams of manganese were present?MW (g/mole): I =126.9; Mn =54.94; Cl = 35.45; K = 39.09; Na = 23; S = 32
The key reaction (unbalanced) in the manufacture of syn-thetic cryolite for aluminum electrolysis is HF(g)+ Al(OH)₃(s) +NaOH(aq) →Na₃AlF₆(aq) +H₂O(l) Assuming a 95.6% yield of dried, crystallized product, whatmass (in kg) of cryolite can be obtained from the reaction of 365 kg of Al(OH)₃, 1.20 m3of 50.0% by mass aqueous NaOH (d=1.53 g/mL), and 265 m³ of gaseous HF at 305 kPa and 91.5°C? (Assume that the ideal gas law holds.)
Explain the separation of Fe2O3 from bauxite with equations
1. What are the practical implications of alloying in carbon and alloy steels? 2. Make use of drawings of segments of the Fe-Cr phase diagram to illustrate the reason for the existence offerritic, martensitic and austenitic stainless steels by also noting the influence of specific alloying elementswhere-applicable. .
Several transition metals are prepared by reduction of themetal halide with magnesium. Titanium is prepared by the Krollmethod, in which ore (ilmenite) is converted to the gaseous chlo-ride, which is then reduced to Ti metal by molten Mg. Assuming yields of 84% for step 1 and 93% for step 2,and an excess of the other reactants, what mass of Ti metal canbe prepared from 21.5 metric tons of ilmenite?
Write balanced net-ionic equations to describe: (a) the reduction of Fe3+ to Fe2+ by SO2 (b) the reaction of H2MoO4 in a Jones reductor (c) the oxidation of HNO2 by a solution of MnO-4. (d) The reaction of aniline (C6H4NH2) with a mixture of KBrO3 and KBr in acidic solution (e) the air oxidation of HAsO2-3 to HasO2-4 (f) the reaction of KI with HNO2 in acidic solution Please answer letters d, e, and f
Consider the reaction between dissolved Fe2+ and elemental sulfur (S0) to form hematite (Fe2O3) and sulfide a) Identify the oxidant and reductant in this reaction, determine half-reactions, and balance thereaction. b) Is this reaction thermodynamically favorable? c) Would you expect HS- to react readily with Fe2O3 (i.e. the reverse of the reaction)?