A sample weighing 1.25 g of the diprotic acid potassium acid phthalate (KHP) is dissolved in 50.0 ml of water. Consider the titration of this solution with 0.100 M NaOH. The two Ka’s for KHP are 1.12 x 10-3 and 3.90 x 10-6.   a. Calculate the pH of this solution before adding any NaOH.   b. How many ml of NaOH must be added to reach the equivalence point? What is the pH at the equivalence point?     c. Calculate the pH of the solution after 100. ml of NaOH have been added.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter15: Acid-base Equilibria
Section: Chapter Questions
Problem 88AE: Consider die titration of 50.0 mL of 0.10 M H3A (Ka1 = 5.0 104, Ka2 = 1.0 108, Ka3 = 1.0 1012)...
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A sample weighing 1.25 g of the diprotic acid potassium acid phthalate (KHP) is dissolved in 50.0 ml of water. Consider the titration of this solution with 0.100 M NaOH. The two Ka’s for KHP are 1.12 x 10-3 and 3.90 x 10-6.

 

a. Calculate the pH of this solution before adding any NaOH.

 

b. How many ml of NaOH must be added to reach the equivalence point? What is the pH at the equivalence point?

 

 

c. Calculate the pH of the solution after 100. ml of NaOH have been added.

 

 

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