A saturated solution of AgI contains 0.05 M KNO3. The Ksp for AgI is 8.3 x 10-17 . As a first approximation, assume that the ionic strength of this solution is dominated by 0.05 M KNO3 Calculate μ. Using the EDH, calculate γAg+ and γI-. Taking activities into account, calculate [Ag+] and [I-] in this solution. Was the approximation in Q20a valid? It not, how could you amend your ionic strength calculation?
A saturated solution of AgI contains 0.05 M KNO3. The Ksp for AgI is 8.3 x 10-17 . As a first approximation, assume that the ionic strength of this solution is dominated by 0.05 M KNO3 Calculate μ. Using the EDH, calculate γAg+ and γI-. Taking activities into account, calculate [Ag+] and [I-] in this solution. Was the approximation in Q20a valid? It not, how could you amend your ionic strength calculation?
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
Problem 74AP
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A saturated solution of AgI contains 0.05 M KNO3. The Ksp for AgI is 8.3 x 10-17 .
- As a first approximation, assume that the ionic strength of this solution is dominated by 0.05 M KNO3 Calculate μ.
- Using the EDH, calculate γAg+ and γI-.
- Taking activities into account, calculate [Ag+] and [I-] in this solution.
- Was the approximation in Q20a valid? It not, how could you amend your ionic strength calculation?
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