a) Show the molecular orbital energy level diagram for o and t interaction of the orbitals in [Mo(CO)] and [Mo(H2O)6]** (Simetry Adapted Orbitals for On: s=a1g, Px=tlu, Py=tlu, Prtlu, dz²=eg, dx²-y=eg, dxy=t2g, dxz=t2g, dyz=t2g). b) Compare stability of the complexes with Ligand Field Theory. c) Explain the order of the CO and H2O ligands in the spectrochemical series
a) Show the molecular orbital energy level diagram for o and t interaction of the orbitals in [Mo(CO)] and [Mo(H2O)6]** (Simetry Adapted Orbitals for On: s=a1g, Px=tlu, Py=tlu, Prtlu, dz²=eg, dx²-y=eg, dxy=t2g, dxz=t2g, dyz=t2g). b) Compare stability of the complexes with Ligand Field Theory. c) Explain the order of the CO and H2O ligands in the spectrochemical series
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter1: Covalent Bonding And Shapes Of Molecules
Section: Chapter Questions
Problem 1.78AP
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