Draw the hybridization for the metal centre of the complex below. You need to determine the geometry before you start, 1. [RhMe(PPh3)3] 2. [RhMe(PMe3)4]

Q: Consider the complex square planar complex NiL4, where Ni2+ (d) is the central ion. Draw the system…

A: Solutions                              Given that Consider the complex  square planer complex.. .…

Q: xplain the complexes below using Ligand Field Theory 1. [RhCl3(OH)3]3- 2. [Cr(en)2(PMe3)2]

A: The electrostatic crystal field theory and the molecular orbital theory were combined into a more…

Q: Suppose you have ML6 - d octahedral complex, calculate The CFSE for a high-spin of this complex: a)…

A: Crystal field stabilization energy or CFSE is a consequence of distribution of electrons in the…

Q: Which cation is mostly likely to form a complex with SCN¯ bonded through the sulfur atom? Nj2+ A]3+…

A: From the concept of HSAB principle we get the answer

Q: Consider an octahedral complex where strong field ligands are bound to a central metal having a d…

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Q: Which complex ion includes a bond angle of 107°? A [Cr(NH;),J** B [CuCl,] C [CuClj?- D [Cr(H,O),1*

A: The Complex [CuCl4]2- exists in a discrete tetrahedral shape. Its crystal structure is taken from…

Q: The complex [Pt(NH3)2(SCN)2] forms two stereoisomerws whereas the complex [Pt(en)(SCN)2] forms only…

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Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe:)4] is a paramagnetic…

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Q: 7. MO Diagram. Consider the molecule [Cr(CO)6]²*. e) bonding (nb), and antibonding (*) orbitals,…

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Q: MeO2C. .CO2M. `N' Mn 'N' .N. MeO2C CO2Me CO2ME

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Q: Determine the hybridization of the metal centre in the complexes below using Ligand Field Theory.…

A: Coordination compounds are those addition molecular compounds which retain their identity in solid…

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

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Q: 12. Sketch the d-orbital energy levels for the following molecular geometries: ligand environment…

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Q: Let’s consider octahedral Sc3+ and Ti3+ complexes.  How many d electrons will each have? Sc3+: 0;…

A: How many d electrons will each have? Sc3+ and Ti3+

Q: Which of the following orders is correct for Tolman cone angles for PR3 ligands? а. РМез > РET3 b.…

A: Tolman Cone angle          → Depends on the basis of steric size . Layer the size layer is the…

Q: According to the Crystal field theory (CFT), Draw the d-orbital splitting diagram for the following…

A: As we know, according to crystal field theory, the interaction between a central metal and an…

Q: According to the Valence Bond Theory [CoCl6] 3-complex ion has 4 unpaired electrons. Accordingly,…

A: Explained as follows

Q: Determine the LFSE in terms of Δ and P for the following complex ions. Be sure to draw the…

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Q: 1. How many isomers of the octahedral complex below? Draw all the isomers! a) [CoBr,ClI2]3-…

A: Isomers are compounds with the same molecular formula but distinct structures, resulting in chemical…

Q: octahedral complex is found to absorb visible light, with the absorption maximum occurring at 507…

A: The absorption with maximum wavelength by an electron is equal to the energy difference between…

Q: which of these complexes will show geometrical isomerism: a  MA2X2 b  MA2XY c  MABCY d  All of these

A: Geometric isomerism:Two or more compounds with the same formula but are having different…

Q: Determine the hybridization of the metal centre in the complexes below using Ligand Field Theory.…

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Q: Given this complex [Co(NH3)Cl(en)2]Cl2 1. What is its systematic name  2. Write down it's…

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Q: Theory [CoCl6] 3-complex ion has 4 unpaired electrons. Accordingly, which of the following…

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Q: How many geometric isomers can exist for the complex [Co(NH3)2Cl2(NO2)2]-

A: This is [Ma2b2c2] type molecule It has 5 geometrical isomar .

Q: Using valence bond theory, explain the following in relation to the complex given below [Cr (CO)6]…

A: VSEPR theory is Valence Shell Electron Pair Repulsion theory.  It helps to find out the…

Q: Use the valence bond theory approach to explain why the Co(NH3)6** ion is a diamagnetic, low-spin…

A: The coordination complexes can be defined as the complex compounds which have a coordinate linkage…

Q: Why can the NH3 molecule serve as a ligand but the BH3 molecule cannot?

A: A ligand is an atom or group of atoms which is linked to a central metal atom or ion in a complex…

Q: 2. Sketch and name two geometrical isomers of [Cr(NH3)2(CO)4]2+ () Is this compound paramagnetic or…

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Q: paramagnetic [NiBr4]^2- and diamagnetic [Ni(Cn)4]2^2- adopt different geometries; give the geometry…

A: Generally those complexes in which central atom attached with weak field ligands have unpaired…

Q: Hexaamminenickel 2 chloride ( [Ni(NH3)6]Cl2 )Explain the hybridization, geometry, and magnetic…

A: [Ni(NH3)6]Cl2 ; In this complex , Ni(28) is present as Ni+2  ion .Ni has valence shell configuration…

Q: how can I explain the complex trans – [CoBr2(en)2] by valence bond theory

A: VBT is the valence bond theory which describes the bonding of the complex in the coordination…

Q: which of the following species are capable of forming a coordination bond with BF3: a  Ca2^+ b  NH3…

A: The following species that are capable of forming a coordination bond with BF3 are to be…

Q: The formations of [cis-PtCl2(NH3)2] and [trans-PtCl2(NH3)2] are different although same ligands are…

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Q: Consider the transition metal M which, in neutral form, has an electronic configuration ending in…

A: Oxidation state is defined as charge on central transition metal ion.

Q: In a trigonal bipyramidal geometry, the electron pairs from the ligands come in along the z-axis…

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Q: calculate the CFSE using Crsytal Field Theory. Compounds: Al(acac)3 , Cr(acac); , Cu(acac)2 a) Name…

A: Valence Bond theory describes covalent bond formation. According to this theory electrons occupy…

Q: Which of the following statements about 10Dq is false? A. In the [CoX(NH3)5]n+ complex, the color…

A: The energy difference in the coordination compound related to colour.In  Strong field ligand,higher…

Q: Answer the following questions for a square planar complex that has a dº metal center. a) What is…

A: The crystal field stabilization energy can be calculated as: CFSE=4(-0.51∆∘)+2(-0.43∆∘)+2(+0.23∆∘)+P…

Q: 6. In the following complex compound there are _ d electrons. [Zn(NH3)4]^2+

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Q: (1I) According to the valence bond theory (VBT) answer the following regarding to [NicIj? complex.…

A: Nickel has 28 Electrons, electronic configuration of 1s2,2s2,2p6,3s2,3p6,4s2, 3d8. While Ni2+ ion…

Q: Which hybridization(s) is/are suitable to form a metal complex? (You can select more than one option…

A: Hybridization which are suitable for metal complex formation are sp, sp2, sp3 , dsp3 . Let's see by…

Q: Name the following complex: [Ni(en)2(F)(NO2)][PtCl3(py)]

A: bis(ethylenediamine)flurido(nitrito-N)nickel(III) trichloridopyridineplatinate(II)

Q: Determine the number of stereoisomers for the octahedral complex [[NiCl2(en)2]? en =H2NCH2CH2NH2,…

A: Total number of isomers is three. There are two geometrical isomer cis and trans.  Trans isomer are…

Q: raw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Since you have posted more than 1 question, we are doing 1st one for you. To do the rest repost the…

Q: 1. How many isomers of the octahedral complex below? Draw all the isomers! a) [CoBr,Cl2I2]3-…

A: Two or more compounds having the same molecular formula but different arrangment of atoms are called…

Q: Predict the geometry and number of unpaired spins inthe following four-coordinate complexes:…

A: Co-ordination compounds: These are the chemical compound formed by donation of electron or charges…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.