Using a group theory approach and the CO bond vectors as your basis determine if MnCl(CO)5 is IR-active
Using a group theory approach and the CO bond vectors as your basis determine if MnCl(CO)5 is IR-active
Want to see the full answer?
Check out a sample Q&A here
Related Chemistry Q&A
Find answers to questions asked by students like you.
Q: Using a group theory approach and the CO bond vectors as your basis determine if Cr(CO)6 is…
A: The point group for the given molecule is Oh and the character table for this point group is shown…
Q: Use the angular overlap method to calculate the metal d-orbital energies for trans-[Cr(NH4);Cl2]*.
A: trans-[Cr(NH4)3Cl2]+ it has trans-octahedral structure.NH3 group is σ donor and Cl is π donor.The…
Q: For an octahedral complex BA6, please determine the point groups of the following structures derived…
A: "Since there are multiple sub-parts in this question and it is not mentioned that which one has to…
Q: Tetrahedral complexes such as [FeF4]2- possess a Td symmetry, as indicated in the picture below. Use…
A: Symmetry operations and symmetry elements are two basic and important concepts in group theory. When…
Q: Q3 a) Calculate the CFSE for the following ions in an octahedral field: Cr2*, Co2*, Mn²+ and Zn²+ ?…
A: CFSE = Crystal Field Stabilization Energy All given metals belongs to 3-d period d orbitals energy…
Q: Calculate the Ligand-field stabilization energies (LFSE) for tetrahedral compounds which contain the…
A: Click to see the answer
Q: Q2 a) Calculate the CFSE for the following ions in an octahedral field: Cr2*, Co2*, Mn²+ and Zn²+ ?…
A: Click to see the answer
Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…
A: Click to see the answer
Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…
A: Geometry of (Rh(me)(pph3)) is square planar with hybridisation dsp2.
Q: 2.Why does K4[NiBr6] behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex…
A: The spontaneous magnetization disappears at the Curie temperature, Tc. Magnetization can still…
Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…
A: Hybridization is the process of mixing up of atomic orbitals to give new orbitals, hybrid orbitals.…
Q: Consider the d' electron configuration of a free ion: a) Calculate the spin multiplicity
A: Click to see the answer
Q: The ligand-field strength also depends on the identity of the central ion, the order being Mn2+ <…
A: Click to see the answer
Q: Using HSAB principle, explain why a large interhalogen species can be stabilized by a large counter…
A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…
Q: 3) The molecule [CuFaJK, has a unique structure (due to jahn-teller distortion) where it has an…
A: Click to see the answer
Q: Draw combinations of orbitals by using all three p orbitals of atom A and all five d orbitals of…
A: The region in the three-dimensional space of an atom and it has a greater probability of finding an…
Q: Which is the strongest reductant: Al, Cu, I-, Al3+, Cu2+, or I2? Explain.
A: A reducing agent is an element or compound that loses an electron to an electron recipient in a…
Q: The molecule (CuFeJKa has a unique structure (due to jahn-teller distortion) where it has an…
A: Click to see the answer
Q: Q6 The two complexes [NiCl4]2 and [PtCl4]² are paramagnetic tetrahedral and diamagnetic square…
A: The geometry of two complexes differ for the central metal ion as ligands are same for the both…
Q: Coordination Geometries Linear L Bent B Trigonal Planar TP Trigonal Pyramidal TPy…
A: The possible geometries of SO32- are,
Q: Draw the orbital splitting diagram for the complex: [Rh(en)3]3+. Rh° : [Kr] 5s²4d7
A: Click to see the answer
Q: how can I explain the complex trans – [CoBr2(en)2] by valence bond theory
A: VBT is the valence bond theory which describes the bonding of the complex in the coordination…
Q: Some different views of an octahedral symmetry metal com
A: There are two types of ligand π acceptor or π acid ligand and sigma donar ya sigma base ligand. The…
Q: raw the hybridization for the metal centre of the complex below. You need to determine the geometry…
A: Since you have posted more than 1 question, we are doing 1st one for you. To do the rest repost the…
Q: Which of the following orders is correct for Tolman cone angles for PR3 ligands? а. РМез > РET3 b.…
A: Tolman Cone angle → Depends on the basis of steric size . Layer the size layer is the…
Q: Draw and fill the molecular orbitals for CO (assume weak sp interactions).
A: The energy of filling of molecular orbitals in the CO molecule is in the order:…
Q: Draw and fill the molecular orbitals for CO (assume weak sp interactions).
A: Molecular orbital diagram represents a picture showing the sharing of electrons between orbitals of…
Q: For the complex [V(H2O)6]2+, the spectroscopic term of the ground state is: Select one: a. 3P b.…
A: The oxidation state of vanadium in the given complex is +2, using this the term symbol is determined…
Q: (a) A complex containing three pyridine and three ammonia ligands bound to a Ni(II) ion was found to…
A: Click to see the answer
Q: Assuming SbCl5 has a trigonal bipyramidal structure , determine the characters for the reducible…
A: Antimony(V) pentachloride has a TBP structure. It is prepared by react chlorine gas into molten…
Q: Which hybridization(s) is/are suitable to form a metal complex? (You can select more than one option…
A: Hybridization which are suitable for metal complex formation are sp, sp2, sp3 , dsp3 . Let's see by…
Q: [Ni (NH3) 6] C12 Explain the hybridization, geometry and magnetic property of the complex structure.
A: Click to see the answer
Q: [Rh(en)3]^3+, Rh^0: [Kr] 5s24d7 Illustrate the orbital splitting diagram for the complex.
A: Click to see the answer
Q: draw structures of the following cations and determine their point groups: 1.…
A: Click to see the answer
Q: Determine the metal–metal bond order consistent with the 18-electron rule for the following: a.…
A: Metal-metal bonds = (18n - VE)/2 Where, n = total number of metal atom in complex VE = total…
Q: NiCl4]2- and Ni(CO)4 have sp3 or dsp2 hybridization? Explain. What type of hybridization is shown by…
A: Click to see the answer
Q: Determine the point groups of the following unit cells: a. Face-centered cubic b. Body-centered…
A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…
Q: 8. Please draw the structures of the following cations and determine their point groups: a.…
A: Click to see the answer
Q: CI..... Cu ***...- Cl Consider the square base pyramidal [CuCls] complex. Using the provided…
A: To determine the reducible representation of any molecule belongs to a point we have to use the…
Q: Which dn electron configurations are expected to undergo a Jahn–Teller distortion in a tetrahedral…
A: Co-ordination compounds are formed when the metal ion is bonded to the ligand which donates its…
Q: About the special type of hybridization involved in complexation (all are correct except Select one:…
A: In different type of hybridization, different type of structures of complexes or coordination…
Q: Select the metal centre with d2sp3 hybridization. a.[Rh(acac)3] b.[RuMe2(bpy)2] c.[RhCl3(PMe3)]…
A: The above problem can be solved using the valancy bond theory. Which states about strong field and…
Q: prove that [Ru(OMe)2(PMe3)4] is a paramagnetic high spin octahedral complex using valence bond…
A: According to valancy bond theory we can say that about the hybridisation of the complexes.…
Q: 37) The angie in the GaBrg molecule is
A: 37. Determination of hybridisation of central atom. x= (V+M-C+A)/2 V = valence electrons of central…
Q: 1. Explain why both cis and trans isomers are possible for [Co(NH3)2(C;O4)2] but only the cis isomer…
A: Since you have asked multiple question, we will solve the first question for you. If you want any…
Q: For the complex [Pt(NH3)2(H2O)2](NO3)2 draw the d-orbital splitting diagram for platinum (high spin…
A: Pt forms square complexes.
Q: Define the terms ligang and coordination sphere.
A: Here are two terms we have to define: Ligand & Coordination sphere
Q: Calculate the total sigma interactions for the four other geometries indicated in the reference…
A: Square Planar Complexes In a square planar, there are four ligands as well. However, the difference…
Q: Predict the magnetic properties and determine the spin-only moment for the following: [Mn(H2O)6]2+…
A: Click to see the answer
Q: Illustrate all possible stereoisomer geometries for the coordination compound, K[Cr(C2O4)2(H2O)e].
A: Click to see the answer
