A solution contains KHCO3, K2CO3 and KOH either alone or in permissible combination. A 50.0 mL aliquot requires 25.0 mL of 0.100 M HCI to reach the phenolphthalein end point. Another 50.0 mL aliquot requires 45.0 mL of the same acid to reach the bromocresol green end point. Which of the following statements BEST describes the composition of the sample solution? O The solution contains more KOH than K2CO3. O The solution contains K2CO3 only. O The solution contains more KHCO3 than K2CO3. O The solution contains a mixture of KHCO3 and KOH. O The solution contains KOH only. O The solution contains more K2CO3 than KOH.

A solution contains KHCO3, K2CO3 and KOH either alone or in permissible combination. A 50.0 mL aliquot requires 25.0 mL of 0.100 M HCI to reach the phenolphthalein end point. Another 50.0 mL aliquot requires 45.0 mL of the same acid to reach the bromocresol green end point. Which of the following statements BEST describes the composition of the sample solution? O The solution contains more KOH than K2CO3. O The solution contains K2CO3 only. O The solution contains more KHCO3 than K2CO3. O The solution contains a mixture of KHCO3 and KOH. O The solution contains KOH only. O The solution contains more K2CO3 than KOH.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter31: Introduction To Analytical Separations

Section: Chapter Questions

Problem 31.17QAP

See similar textbooks

Similar questions

A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
A bottle of concentrated hydroiodic acid is 57% HI by weight and has a density of 1.70 g/mL. A solution of this strong and corrosive acid is made by adding exactly 10.0 mL to some water and diluting to 250.0 mL. If the information on the label is correct, what volume of 0.988 M NaOH is needed to neutralize the HI solution? Suggest an indicator for the titration.
Isocyanic acid (HNCO) can be prepared by heating sodium cyanate in the presence of solid oxalic acid according to the equation 2NaOCN(s)+H2C2O4(s)2HNCO(l)+Na2C2O4(s) Upon isolating pure HNCO(l), an aqueous solution of HNCO can be prepared by dissolving the liquid HNCO in water. What is the pH of a l00.-mL solution of HNCO prepared from the reaction of 10.0 g each of NaOCN and H2C2O4, assuming all of the HNCO produced is dissolved in solution? (Ka of HNCO = 1.2 l04.)
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
What is the pH of a solution made by mixing 0.30 molNaOH, 0.25 mol Na2HPO4, and 0.20 mol H3PO4 with waterand diluting to 1.00 L?
calculate the pH of a solution prepared by adding 20.0 mL of 0.500M CH3COOH with 21.43 mL of 0.500 M NaOH. Ksp of CH3COOH is 1.8x10^-5
What is the percentage of total acid expressed as acetic acid (CH3COOH) in a sample of vinegar if 3.000 g of the vinegar require 20.50 mL of 0.1150 N KOH solution for an end point with phenolphthalein indicator?
A solution of volume 0.500 L contains 1.68 g NH3 (Kb = 1.8 x 10^-5) and 4.05 g (NH4)2SO4. How many milliliters of 12 M HCI must be added to 0.500 K of the original solution to change its pH to 9.00?
How many mL of 0.112M Pb(NO3)2 are needed to completely react with 25.0mL of 0.105M KI? Given: Pb(NO3)2 + 2KI -> PbI2 + 2KNO3.
Calculate the volume (mL) of 0.100M H3PO4 required to neutralize 25.0 mL of 0.010M Ca(OH)2 .
What volume of 0.317M KOH solution will be required to titrate 25.00mL of 0.285M HNO3? What mass of Ca(OH)2 is required to neutralize 5.00mL of 0.180M HCl?