A solution contains three anions with the following concentrations: 0.20 M CrO42 - , 0.10 M CO32 - , and 0.010 M Cl-. If a dilute AgNO3 solution is slowly added to the solution, what is the first compound to precipitate: Ag2CrO4 (Ksp = 1.2 * 10-12), Ag2CO3 (Ksp = 8.1 * 10-12), or AgCl (Ksp = 1.8 * 10-10)?

Fundamentals Of Analytical Chemistry
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Chapter11: Solving Equilibrium Problems For Complex Systems
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Problem 11.16QAP
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A solution contains three anions with the following concentrations: 0.20 M CrO42 - , 0.10 M CO32 - , and 0.010 M Cl-. If a dilute AgNO3 solution is slowly added to the solution, what is the first compound to precipitate: Ag2CrO4 (Ksp = 1.2 * 10-12), Ag2CO3 (Ksp = 8.1 * 10-12), or AgCl (Ksp = 1.8 * 10-10)?

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