A solution is 0.0111 M in both Br– and SO42–. A 0.283 M solution of lead(II) nitrate is slowly added to it with a buret. The (Br- or  SO4^2-)  anion will precipitate from solution first. (Ksp for PbBr2 = 6.60 ×× 10–6; Ksp for PbSO4 = 2.53 ×× 10–8)   What is the concentration in the solution of the first anion when the second one starts to precipitate at 25°C?

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter15: Additional Aqueous Equilibria
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A solution is 0.0111 M in both Br and SO42–. A 0.283 M solution of lead(II) nitrate is slowly added to it with a buret.

The (Br- or  SO4^2-)  anion will precipitate from solution first.

(Ksp for PbBr2 = 6.60 ×× 10–6Ksp for PbSO4 = 2.53 ×× 10–8)

 

What is the concentration in the solution of the first anion when the second one starts to precipitate at 25°C?

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