a) The second virial coefficient of ammonia at 298.15K is -261 cm³ mol Calculate the molar volume and the compressibility factor of ammonia at this temperature and a pressure of 0.5 MPa (1 MPa = 1 x 106 Pa). Assume that at the given temperature and pressure, the terms with higher virial coefficients are negligible.

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a) The second virial coefficient of ammonia at 298.15 K is -261 cm³ mol-1. Calculate the
molar volume and the compressibility factor of ammonia at this temperature and a pressure of
0.5 MPa (1 MPa = 1x 106 Pa). Assume that at the given temperature and pressure, the terms
with higher virial coefficients are negligible.
b) Using the van der Waals equation of state calculate the pressure and compressibility factor
of a substance whose critical temperature is 800 K and critical pressure is 8.314 MPa (at a
temperature of 1000 K and a molar volume of 1100 cm³ mol-1.
Transcribed Image Text:Question 2 a) The second virial coefficient of ammonia at 298.15 K is -261 cm³ mol-1. Calculate the molar volume and the compressibility factor of ammonia at this temperature and a pressure of 0.5 MPa (1 MPa = 1x 106 Pa). Assume that at the given temperature and pressure, the terms with higher virial coefficients are negligible. b) Using the van der Waals equation of state calculate the pressure and compressibility factor of a substance whose critical temperature is 800 K and critical pressure is 8.314 MPa (at a temperature of 1000 K and a molar volume of 1100 cm³ mol-1.
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