An experiment is conducted in which a quantity of H2(g) is chemically generated in a closed headspace of volume V1 at absolute temperature T1, thereby raising the total pressure from Pa (the initial air pressure) to Pf (the total final pressure of H2(g) + air). Compose an algebraic expression for the volume (V2) that this sample of H2(g) would occupy if it were isolated (pure -- i.e. no air) at absolute temperature T2 and partial pressure P2. Note that your expression may contain no other variables than those given above, namely: V1, T1, T2, Pa, Pf, and P2. A) V2 = Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP. B) VM =

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Chapter5: The Gaseous State
Section: Chapter Questions
Problem 5.127QP: A 1.000-g sample of an unknown gas at 0C gives the following data: P(atm) V (L) 0.2500 3.1908 0.5000...
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An experiment is conducted in which a quantity of H2(g) is chemically generated in a closed headspace of volume V1 at absolute temperature T1, thereby raising the total pressure from Pa (the initial air pressure) to Pf (the total final pressure of H2(g) + air). Compose an algebraic expression for the volume (V2) that this sample of H2(g) would occupy if it were isolated (pure -- i.e. no air) at absolute temperature T2 and partial pressure P2.


Note that your expression may contain no other variables than those given above, namely: V1T1T2PaPf, and P2.

A) V2 =

Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP.

B) VM =

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Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP.

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