In general, the compressibility factor Z tends to be larger than 1 at very high pressures (greater than 350 bar for methane.) Which Van der Waals' factor seems to be responsible for this behavior.--- a or b?  Explain

Physical Chemistry
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ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.24E
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In general, the compressibility factor Z tends to be larger than 1 at very high pressures (greater than 350 bar for methane.) Which Van der Waals' factor seems to be responsible for this behavior.--- a or b?  Explain

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