(a) Which of the following polymers (i) – (vi) exist in different stereochemical forms? Draw polymer structures of all the stereoregular forms that are possible for each of the polymers. (i) polyethylene (ii) poly(1-butene) (iii) poly(2-methylpropene) (polyisobutylene) (iv) poly(vinyl fluoride) (v) poly(vinylidine fluoride) (vi) poly(1,3-pentadiene) (b) Explain why high molecular weight polypropylene is optically inactive, despite having an asymmetric center at every other carbon atom, while in contrast, poly(propylene oxide) is optically active

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter23: Carbon: Not Just Another Element
Section: Chapter Questions
Problem 4PS
icon
Related questions
Question

(a) Which of the following polymers (i) – (vi) exist in different stereochemical forms? Draw polymer structures of all the stereoregular forms that are possible for each of the polymers.

(i) polyethylene (ii) poly(1-butene) (iii) poly(2-methylpropene) (polyisobutylene) (iv) poly(vinyl fluoride) (v) poly(vinylidine fluoride) (vi) poly(1,3-pentadiene)

(b) Explain why high molecular weight polypropylene is optically inactive, despite having an asymmetric center at every other carbon atom, while in contrast, poly(propylene oxide) is optically active.

Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Types of Polymers on the Basis of Physical Properties
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305580350
Author:
William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:
Cengage Learning