a. b. Credit: Smith, Organic Chemistry • Build the model of each E2 elimination product. • Take a photo and upload into this assignment. References:
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- Predict the major substitution products of the following reaction. Br. H Na OAc HOAC • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If there is more than one major product possible, draw all of them. H.C. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the sign from the drop-down menu. Q24 DO-Sall ⒸY 981 BEH O. IF1. Identify each move below as attack, leave, protonate (or deprotonate), or rearrang e. A. B. н- но- O-H н.8н н,о° +] D.[ E. F.Be sure to answer all parts. Draw a stepwise mechanism for the following reaction: OH H,SO, Part 1: A. HSO, for B. H,SO, C. H20 view structure view structure SO2 Part 2 out of 4 OA. H;O" OB. . H,O Oc. Oc. HO draw structure... finish structure OD. H2 報 Next part +.
- 4. Provide the missing reagent(s) and major product(s) for the following reactions. a. a.ii. b. НО. A + B a.i. H₂SO4 (conc.), A pyridine a.iii. HO a.iv. CI OH A BRank the species in each group in order of increasing nucleophilicity. a. CH,, "OH, "NH2 b. H20, OH, "SH in CH3OH c. CH,CH2S", CH;CH2O¯, CH;COO" in CH3OH d. CH3NH2, CH3SH, CH;OH in acetone e. "OH, F", CI" in acetone f. HS, F", CI in CH3OHMatch each reaction to a product. Answers may be repeated. Assume any necessary workup. Chiral products are racemic. D stands for deuterium, an isotope of hydrogen. OH a. b. OH d. e. not a.-d. NABD, Choose. BD3 NaOOH Choose.
- 3.a. When the addition reaction is done below, only one product is formed. What is that product? Include stereochemistry. Show mechanism for first step only; no mechanism for second step. 3.b. Why is this the only product formed? Me. .Me Z Me 1) BH3, THF show stereochemistry 2) H₂O₂, NaOH, H₂O no mechanism for this step16 eBook Print References Be sure to answer all parts. Draw a stepwise mechanism for the following reaction: Part 1 out of 3 finish structure ... 10 attempts left OH HBr draw structure... Check my work Br HBr H₂O HOBr Br HO™ Next partWhich reaction(s) would occur in the reaction below (substitution, elimination, both, or neither)? H2O O a. SN1 Ob.SN2 O c. SN1 & E1 O d. SN2 & E2 O e. E1 O f. E2 O g. No reaction
- 4. Circle the electrophilic and nucleophilic atoms in each substitution reaction below. Provide the neutral organic product; where a stereocenter is created, use a wavy bond to indicate a mixture of configurations or wedges/dashes for stereospecific reactions. Also, provide the dominant reaction mechanism (Sn2 or SN1) somewhere in each box. A. Br NaSEt DMF В. ELOH C. .SO2NHNA Cl + D. NaH Br- HO, DMFBased on your knowledge in biological chemistry reaction in biomolecules, what do you think is the best type and product for the above reaction? a. SN1 b. SN2 c. E1 d. E2 e. None of the aboveDraw the products of each reaction. CHO Br. OCH3 Br2 so3 a. -CN i. H2SO, FeBr3 H2SO4 CH3 NaSCH,CH3 CH,COCI j. AICI3 HNO. b. f. -NHCOCH, -F H2SO, "NO2 CH3O но NO2 CH3 NO2 So3 H2SO, HNO3 H2SO, C. HO. NO2 CH;CH,CI AICI Cl2 d. C- -ососн h. CH;0- -COOCH3 FeCla