a. Calculate ΔH°f for methane (you will need to dust off Hess’s Law for this one, and recall that the heat of formation, ΔH°f , is the amount of energy required to form 1 mol of a substance from the elements under standard conditions- start by writing a balanced equation for this process.). b. From appropriate entropy data, calculate ΔS°f for methane. c. Use the above information to calculate ΔG°f for methane. d. Compare your results from part C with the reported ΔG°f for methane

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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a. Calculate ΔH°f for methane (you will need to dust off Hess’s Law for this one, and recall that the heat of formation, ΔH°f , is the amount of energy required to form 1 mol of a substance from the elements under standard conditions- start by writing a balanced equation for this process.).

b. From appropriate entropy data, calculate ΔS°f for methane.

c. Use the above information to calculate ΔG°f for methane.

d. Compare your results from part C with the reported ΔG°f for methane

Selected thermodynamic data at 298 K.
Substance
AH°t (kJ/mol)
AG°f (kJ/mol)
S° J/mol-K)
PC13(g)
-319.6
-272.4
217
Oz(g)
205.0
POC1:(g)
-542.2
-502.5
325
C(graphite)
5.69
H2(g)
130.58
CH4(g)
?
-50.8
186.3
Transcribed Image Text:Selected thermodynamic data at 298 K. Substance AH°t (kJ/mol) AG°f (kJ/mol) S° J/mol-K) PC13(g) -319.6 -272.4 217 Oz(g) 205.0 POC1:(g) -542.2 -502.5 325 C(graphite) 5.69 H2(g) 130.58 CH4(g) ? -50.8 186.3
ΔΗ(Κ)
CO2(8) + 2H2(8) →> CH2O(g) + H2O(g)
CO2(8) → C(graphite) + O2(g)
CH2O(g) + 2H2(3) → CH«(8) + H2O(g)
2H2(g) + O2(8) → 2 H2O(g)
35.5
393
-201
-484
Transcribed Image Text:ΔΗ(Κ) CO2(8) + 2H2(8) →> CH2O(g) + H2O(g) CO2(8) → C(graphite) + O2(g) CH2O(g) + 2H2(3) → CH«(8) + H2O(g) 2H2(g) + O2(8) → 2 H2O(g) 35.5 393 -201 -484
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