6.48 Diamond and graphite are two crystallıne forms of 1 atm and 25°C, diamond changes to graphite so slowly that the enthalpy change of the process must be obtained indirectly. Using equations from the numbered list below, determine AH for C(diamond) C(graphite) CO(g) AH = -395.4 kJ (1) C(diamond) + O,(g) – (2) 2CO,(g) – 2C0(g) + 0,(g) (3) C(graphite) + O2(8) – (4) 2CO(g) > ΔΗ- 566.0 kJ %3D CO,(g) AH = -393.5 kJ %3D C(graphite) + CO,(g) AH = -172.5 kJ %3D

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Chapter6: Thermochemisty
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Problem 6.119QP: Calcium oxide, CaO, is prepared by heating calcium carbonate (from limestone and seashells)....
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6.48 Diamond and graphite are two crystalline forms of carbon. At
1 atm and 25°C, diamond changes to graphite so slowly that the m
enthalpy change of the process must be obtained indirectly. Using
equations from the numbered list below, determine AH for
wi C(diamond)
C(graphite) o
(1) C(diamond) + O2(8)
→ CO,(g) AH = -395.4 kJ
(2) 2CO,(g)
ΔΗ
566.0 kJ
2CO(g) + O2(g)
CO-(g)
(3) C(graphite) + O2(8)
(4) 2CO(g)
AH = -393.5 kJ
>
C(graphite) + CO,(g) AH = -172.5 kJ
Transcribed Image Text:6.48 Diamond and graphite are two crystalline forms of carbon. At 1 atm and 25°C, diamond changes to graphite so slowly that the m enthalpy change of the process must be obtained indirectly. Using equations from the numbered list below, determine AH for wi C(diamond) C(graphite) o (1) C(diamond) + O2(8) → CO,(g) AH = -395.4 kJ (2) 2CO,(g) ΔΗ 566.0 kJ 2CO(g) + O2(g) CO-(g) (3) C(graphite) + O2(8) (4) 2CO(g) AH = -393.5 kJ > C(graphite) + CO,(g) AH = -172.5 kJ
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