a. Calculate the ee of a solution with the following [a] values: -50, –83, and -120. b. For each ee, calculate the percent of each enantiomer present. c. What is [a] for the enantiomer of quinine? d. If a solution contains 80% quinine and 20% of its enantiomer, what is the ee of the solution? e. What is [a] for the solution described in part (d)?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter16: Aldehydes And Ketones
Section: Chapter Questions
Problem 16.71P
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The [a] of pure quinine, an antimalarial drug, is –165.
a. Calculate the ee of a solution with the following [a] values: –50, –83, and –120.
b. For each ee, calculate the percent of each enantiomer present.
c. What is [a] for the enantiomer of quinine?
d. If a solution contains 80% quinine and 20% of its enantiomer, what is the ee of
Но
е ее
the solution?
CH30
e. What is [a] for the solution described in part (d)?
N
quinine
(antimalarial drug)
Transcribed Image Text:The [a] of pure quinine, an antimalarial drug, is –165. a. Calculate the ee of a solution with the following [a] values: –50, –83, and –120. b. For each ee, calculate the percent of each enantiomer present. c. What is [a] for the enantiomer of quinine? d. If a solution contains 80% quinine and 20% of its enantiomer, what is the ee of Но е ее the solution? CH30 e. What is [a] for the solution described in part (d)? N quinine (antimalarial drug)
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