Chapter20: Nucleophilic Substitution Reactions: Competing Nucleophiles
Section: Chapter Questions
Problem 4Q
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Question
Trabectedin, shown in a ball-and-stick model on the cover of this text, is an anticancer drug sold under the trade name Yondelis.
a. Locate the stereogenic centers in trabectedin.
b.What is the maximum number of stereoisomers possible for trabectedin?
c.Draw the enantiomer.
d.Draw a diastereomer.
e.If the specific rotation of trabectedin is +41.5, what is the [α] of a solution that contains 75% trabectedin and 25% of its enantiomer?f
. What is the ee of a solution with [α] = +10.5?
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