a. Calculate the heat required to melt 8.02 g of benzene at its normal melting point. Heat of fusion (benzene) = 9.92 kJ/mol Heat = kJ b. Calculate the heat required to vaporize 8.02 g of benzene at its normal boiling point. Heat of vaporization (benzene) = 30.7 kJ/mol Heat = kJ c. Why is the heat of vaporization more than three times the heat of fusion? O In the liquid state, intermolecular forces must be broken, while in the solid state intramolecular forces must be broken. O Forces holding molecules in the liquid state are much stronger than in the solid state. O More energy is required to overcome the forces holding the molecules together in the liquid state (/ to g) than to just allow the molecules to begin moving (s to /)

Chemistry: An Atoms First Approach
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Chapter9: Liquids And Solids
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Problem 98E
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a. Calculate the heat required to melt 8.02 g of benzene at its normal melting point.
Heat of fusion (benzene) = 9.92 kJ/mol
Heat =
kJ
b. Calculate the heat required to vaporize 8.02 g of benzene at its normal boiling point.
Heat of vaporization (benzene)
= 30.7 kJ/mol
Heat =
kJ
c. Why is the heat of vaporization more than three times the heat of fusion?
In the liquid state, intermolecular forces must be broken, while in the solid state intramolecular forces must be broken.
Forces holding molecules in the liquid state are much stronger than in the solid state.
More energy is required to overcome the forces holding the molecules together in the liquid state (/ to g) than to just allow the molecules to begin moving (s to /).
Transcribed Image Text:a. Calculate the heat required to melt 8.02 g of benzene at its normal melting point. Heat of fusion (benzene) = 9.92 kJ/mol Heat = kJ b. Calculate the heat required to vaporize 8.02 g of benzene at its normal boiling point. Heat of vaporization (benzene) = 30.7 kJ/mol Heat = kJ c. Why is the heat of vaporization more than three times the heat of fusion? In the liquid state, intermolecular forces must be broken, while in the solid state intramolecular forces must be broken. Forces holding molecules in the liquid state are much stronger than in the solid state. More energy is required to overcome the forces holding the molecules together in the liquid state (/ to g) than to just allow the molecules to begin moving (s to /).
Expert Solution
Step 1

Given data,

Mass of benzene = 8.02 g

Heat of fusion = 9.92 kJ/mol

Heat of vaporization = 30.7 kJ/mol

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