a. Calculate the relative number of hydrogen atoms from all the peaks and integration values provided in the NMR spectrum. b. Calculate the multiplicity of all the peaks resulting from your suspected structural formulas. c. Calculate the chemical shifts of all the peaks resulting from your suspected structural formulas.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter13: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 13.28P
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a. Calculate the relative number of hydrogen atoms from all the peaks and integration values provided in the NMR spectrum.

b. Calculate the multiplicity of all the peaks resulting from your suspected structural formulas.

c. Calculate the chemical shifts of all the peaks resulting from your suspected structural formulas. 

Benchmark chemical shifts values of various groups
Methyl
Methylene
Methine
H
-C-H
-C-H
H
0.9 ppm
1.2 ppm
1.7 ppm
Transcribed Image Text:Benchmark chemical shifts values of various groups Methyl Methylene Methine H -C-H -C-H H 0.9 ppm 1.2 ppm 1.7 ppm
Proton NMR Spectrum
Triplet
8 = 1.1
Singlet
8 = 2.1
integration
Integration Value = 3.04
Value
2.96
Quartet
6 = 2.5
Integration Value = 1.99
11
10
7 6 5
4
3 2
Chemical Shift "8 " (ppm)
00
Transcribed Image Text:Proton NMR Spectrum Triplet 8 = 1.1 Singlet 8 = 2.1 integration Integration Value = 3.04 Value 2.96 Quartet 6 = 2.5 Integration Value = 1.99 11 10 7 6 5 4 3 2 Chemical Shift "8 " (ppm) 00
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