3. a. (i) Starting from K₂[PtC14], plan synthetic routes to the two complexes A and B shownbelow, using your knowledge of the trans effect. Formulate each step by drawingstructures of each complex and give a full explanation for your choices. Make sureto assign the correct charges to each complex in each case.7-7-(ii)NCSNH₂-Pt-BrCINO₂CI-Pt-OHCOBWrite a detailed discussion of the two factors that may contribute to the overalltrans-directing ability of a particular ligand, considering thermodynamic andkinetic aspects. Use appropriate examples and orbital sketches to support yourexplanations.

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a. (i) Starting from K2₂[PtC14], plan synthetic routes to the two complexes A and B shown below, using your knowledge of the trans effect. Formulate each step by drawing structures of each complex and give a full explanation for your choices. Make sure to assign the correct charges to each complex in each case. 7- 7. (ii) NH₂ NCS- -Pt-Br NO₂ CI-Pt-OH CO Write a detailed discussion of the two factors that may contribute to the overall trans-directing ability of a particular ligand, considering thermodynamic and kinetic aspects. Use appropriate examples and orbital sketches to support your

a. (i) Starting from K2₂[PtC14], plan synthetic routes to the two complexes A and B shown below, using your knowledge of the trans effect. Formulate each step by drawing structures of each complex and give a full explanation for your choices. Make sure to assign the correct charges to each complex in each case. 7- 7. (ii) NH₂ NCS- -Pt-Br NO₂ CI-Pt-OH CO Write a detailed discussion of the two factors that may contribute to the overall trans-directing ability of a particular ligand, considering thermodynamic and kinetic aspects. Use appropriate examples and orbital sketches to support your

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.17QAP

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