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- 1. What is the molar solubility of PbCl2 in a solution of 0.23 M CaCl2? Ksp = 1.6 ✕ 10-5 for PbCl2. 2. What is the Qsp when 32.0 mL of 6.50 ✕ 10-7 M Na3PO4 are mixed with 41.4 mL of 5.50 ✕ 10-5 M CaCl2? Assume the volumes are additive. Ksp = 2.0 ✕ 10-29. 3. What is the Qsp when 61.0 mL of 1.50 ✕ 10-4 M AgNO3 are mixed with 80.0 mL of 5.20 ✕ 10-3 M CaCl2? Assume the volumes are additive. Ksp = 1.6 ✕ 10-10. 4. What [I-1] is needed to start the precipitation of AgI from a saturated solution of AgCl? Ksp = 2.9 ✕ 10-16 for AgI and Ksp = 1.2 ✕ 10-10 for AgCl.A local company sent you their green alternative for window cleaner to be tested for percent (w/v) acetic acid content. For your experiment, you first standardized your NaOH titrant with 0.8053 g of (99.80 % purity) KHP. You used 40.60 mL of NaOH for your standardization. After that you then analyzed a 10.00 mL sample and found that you needed 43.20 mL NaOH to reach the end point. Summary of results: Standardization Sample analysis KHP Weight (g) 0.8053 g Volume of sample 50.00 mL Purity 99.80% NaOH (mL) used 33.20 mL NaOH (mL) used 40.60 mL Determine the following: Molarity of NaOH % (w/v) acetic acid1. 1093-g sample of impure Na2CO3 was analyzed by residual precipitimetry. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back-titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the endpoint. The percentage Na2CO3 (MW = 106.0 g/mole) in the tested sample is ________ % ? Note: Express final answer using least number of significant figures. 2. The alkalinity of natural waters is usually controlled by OH- (MW = 17.01 g/mole), CO3-2 (MW = 60.01 g/mole), and HCO3- (MW = 61.01 g/mole), which may be present singularly or in combination. Titrating a 10.0-mL sample to a phenolphthalein endpoint requires 38.12 mL of a 0.5812 M solution of HCl, and an additional 18.67 mL of the same titrant to reach the methyl orange endpoint. The composition of the sample is _________% CO3-2 and ___________ % OH- Note: Express final answers using least number of significant figures.
- A Fajans titration of a 0.7908-g sample required 45.32 mL of 0.1046 M AgNO3 . Express the results of this analysis in terms of the percentage of BaCl2 * H2O. (Use a MW value in 4 decimal places)PART 2: A solution is prepared by mixing 150.0 mL of 0.0010 M magnesium nitrate and 250.0 mL of 0.100 M sodium fluoride (Ksp = 7.4x10-11). Is Ksp greater than , equal to, or lower than Qsp? Will a precipitate form, Y/N? What is the fluoride ion concentration (in solution) after mixing is complete? Give your answer in exponential form and to three sig. figs. (e. g. 1.23E-3). What is the magnesium ion concentration (in solution) after mixing is complete? Give your answer in exponential form and to three sig. figs. (e. g. 1.23E-3).175.0 mL of 0.2015 M nitric acid was added to 1.4213 g of impure calcium carbonate sample. The excessacid was back titrated with 72.5mL of 0.1152 M sodium hydroxide to reach the endpoint. Calculate for thepercent calcium carbonate? (MM of CaCO3= 100.0869 g/mol)2HNO3 + CaCO3 → Ca(NO3)2 + H2O + CO2HNO3 + NaOH → NaNO3 + H2O
- Calcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)pls complete table given the data Determination of Ksp and Molar Solubility1. Add Ca(OH)2 to 250.0 mL distilled water with stirring until equilibrium is achieved. 2. Filter the undissolved precipitate. Measure out 50.0 mL of the supernate into a 250-mL Erlenmeyer flask using a pipette.3. Add a few drops of phenolphthalein indicator and titrate with standardized HCl solution until endpoint is achieved.4. Record the volume the HCl solution used. Perform two more trials.In order to form Ba(IO3)2, 500 mL of 0.5000 M Ba(NO3)2 was mixed with 500 mL of 0.0500 M NaIO3. Ksp= 1.57x10^-9What is the concentration of the excess reagent?What is the molar solubility of Ba(IO3)2 in this solution? 2.04x10^-5 M 4.07x10^-5 M 6.15x10^-5 M 8.30x10^-5 M
- 0.9563 g KHCO3 (M.r.(KHCO3) = 100.12 g/mol (mg/mmol)) have measured, and 50.0 cm3 stock solution have been prepared from it. 10.00 cm3 individual samples from it was titrated with HCl titrant in order to determine its concentration. The average HCl consumption was 19.18 cm3. The same HCl solution with were used to determine the concentration of NaOH titrant. The base consumption for 20.00 cm3 HCl was 21.35 cm3 NaOH. 1. concentration of HCl 2. concentration of NaOHA 1.067g sample of magnesium oxide of 84.736% were treated with 50mL of 1.017 N Sulfuric Acid, and a 5.195mL volume of sodium hydroxide is required in the back titration. 1. What is the equivalent weight consumed by the acidic titrant? A. 5.281 g-meq B. 55.150 g-meq C. 5.723 g-meq D. 50.850 g-meq 2. What is the difference of milliequivalent weight consumed in the reaction? A. 45.127g-meq B. 56.573g-meq C. 50.850g-meq D. 55.150g-meq 3. What is the amount (in mg) of the analyte that is equivalent to 1 milliliter of the tirant at its equivalence point? A. 22.060mg B. 40.680mg C. 44.12mg D. 20.340mgPart 1: Preparation of the Primary Citric Acid Standard Mass of Citric Acid: 4.05 g Volume of Citric Acid Solution: 7.5 (at the equivalence point) Moles of Citric Acid: 0211 mol (Molar Mass = 192.0 g/mol) Molarity of Citric Acid Solution: 0.2813 help me with part Part 2: Titration of the Sodium Hydroxide Solution Volume of Citric Acid at the Equivalence Point _____________ Moles of Citric Acid at the Equivalence Point _______________ Moles of NaOH at the Equivalence Point __________________ 3 NaOH + H3C6H5O7 à Na3C6H5O7 + 3 H2O Volume of NaOH _______________________________ 5. Calculated Molarity of NaOH _______________________