Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron pushing arrows for the following reaction or mechanistic steps. Be sure to account for all bond-breaking and bond-making steps. 15.:D:•NiOH:H-NEadd arows here#₂0Ladd arows here(CH2CH2)2NH,(CH3CH2)2NHadd wrows here(CHSCH2)2 NH2HIN² ( ² HR EH5)(CH3CHz)는 NHz+SCHỊCH)2NH+(CH3CH2)2 NHCHỊCH NH+H12•OH®9:0H€add arrows here(CH,CH2)2NH,CCHCH2NHHHI.N:add arows hereHH #HHFinal Product:0°Něadd arows here(H3CH2)2NHCH, CH2NHRoweH+-HH-H

Given reaction is enamine formation . Ketone and amine reacts to form enamine . And in reaction…

add arows here HO: H-NE 4-№ add arows here 7 (CHCH2)2NH,t (CH3CH2)2NH CHỊCH add arows here (CH3CH2)2NH2 (CH3CH2NH (CH3CHzz NHz+ LCH CHANH (CH3CH2)2 NH CHỊCH ĐỊNH a dd TL H-N: anows here LCHICH2)2NH, CCH, CHI NH add arows here #H + H H Final Product B add arnows here (HCH2)2NH CHỊCH 22NH H :0 H. H

add arows here HO: H-NE 4-№ add arows here 7 (CHCH2)2NH,t (CH3CH2)2NH CHỊCH add arows here (CH3CH2)2NH2 (CH3CH2NH (CH3CHzz NHz+ LCH CHANH (CH3CH2)2 NH CHỊCH ĐỊNH a dd TL H-N: anows here LCHICH2)2NH, CCH, CHI NH add arows here #H + H H Final Product B add arnows here (HCH2)2NH CHỊCH 22NH H :0 H. H

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter10: Oxidation And Reduction

Section: Chapter Questions

Problem 4CTQ

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