Ammonia and potassium iodide solutions are added to an aqueous solution of chromium(III) nitrate. A solid is isolated (compound A) and the following data are collected: When 0.105 g of compound A was strongly heated in excess oxygen, 0.0203 g of chromium(VI) oxide was formed. In a second experiment it took 32.93 mL of 0.100M HCl to titrate completely the ammonia present in 0.341 g of compound A. Compound A was found to contain 73.53% iodine by mass. The freezing point of water was lowered by 0.62oC when 0.601 g of compound A was dissolved in 10.00 g of water.   What is the formula of the compound A?

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Chapter21: Chemistry Of The Main-group Elements
Section: Chapter Questions
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  1. Ammonia and potassium iodide solutions are added to an aqueous solution of chromium(III) nitrate. A solid is isolated (compound A) and the following data are collected:
  • When 0.105 g of compound A was strongly heated in excess oxygen, 0.0203 g of chromium(VI) oxide was formed.
  • In a second experiment it took 32.93 mL of 0.100M HCl to titrate completely the ammonia present in 0.341 g of compound A.
  • Compound A was found to contain 73.53% iodine by mass.
  • The freezing point of water was lowered by 0.62oC when 0.601 g of compound A was dissolved in 10.00 g of water.

 

What is the formula of the compound A?

 

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