Ammonia has a normal (1.00atm) boiling point of -33.3*C. Under a pressure of 2.11 atm, what is ammonia's boiling point in *C? For ammonia delta vaporization= 23.3kJ/mol.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter11: Liquids And Solids
Section: Chapter Questions
Problem 11.42QE
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Ammonia has a normal (1.00atm) boiling point of -33.3*C. Under a pressure of 2.11 atm, what is ammonia's boiling point in *C? For ammonia delta vaporization= 23.3kJ/mol.

Expert Solution
Step 1

Vapor pressure at normal boiling point (P1) = 1 atm

Normal boiling point (T1) = - 33.3 oC = (273 - 33.3) = 239.7 K

Vapor pressure  (P2) = 2.11 atm

R = gas constant = 8.314 J/K mol

Enthalpy of vaporization = 23.3 kJ/mol

Enthalpy of vaporization = 23300 J/mol

T2 => boiling point at 2.11 atm=?

 

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