An analytical chemist weighs out 0.131 g of an unknown monoprotic acid into a 250 mL volumetric flask and dilutes to the mark with distilled water. He then titrates this solution with 0.1200 M NaOH solution. When the titration reaches the equivalence point, the chemist finds he has added 11.6 mL of NaOH solution. Calculate the molar mass of the unknown acid. Round your answer to 3 significant digits. 0 mol X ? 00 B 00 E

An analytical chemist weighs out 0.131 g of an unknown monoprotic acid into a 250 mL volumetric flask and dilutes to the mark with distilled water. He then titrates this solution with 0.1200 M NaOH solution. When the titration reaches the equivalence point, the chemist finds he has added 11.6 mL of NaOH solution. Calculate the molar mass of the unknown acid. Round your answer to 3 significant digits. 0 mol X ? 00 B 00 E

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter15: Solutions

Section: Chapter Questions

Problem 62QAP

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Sulfuric acid is listed in a catalog with a concentration of 95-98%. A bottle of the acid in the stockroom states that 1.00 L has a mass of 1.84 kg. To determine the concentration of sulfuric acid in the stockroom bottle, a student dilutes 5.00 mL to 500. mL She then takes four 10.00-mL samples and titrates each with standardized sodium hydroxide (c = 0.1760 M). (a) What is the average concentration of the diluted sulfuric acid sample? (b) What is the mass percent of H2SO4 in the original bottle of the acid?
You have 250. mL of 0.136 M HCl. Using a volumetric pipet, you take 25.00 mL of that solution and dilute it to 100.00 mL in a volumetric flask. Now you take 10.00 mL of that solution, using a volumetric pipet, and dilute it to 100.00 mL in a volumetric flask. What is the concentration of hydrochloric acid in the final solution?
Two students titrate different samples of the same solution of HCl using 0.100 M NaOH solution and phenolphthalein indicator (Figure 4.12). The first student pipets 20.0 mL of the HCl solution into a flask, adds 20 mL of distilled water and a few drops of phenolphthalein solution, and titrates until a lasting pink color appears. The second student pipets 20.0 mL of the HCl solution into a flask, adds 60 mL of distilled water and a few drops of phenolphthalein solution, and titrates to the first lasting pink color. Each student correctly calculates the molarity of an HCl solution. What will the second students result be? (a) four times less than the first students result (b) four times greater than the first students result (c) two times less than the first students result (d) two times greater than the first students result (e) the same as the first students result
Titration of a 20.0-mL sample of acid rain required 1.7 mL of 0.08 11 M NaOH to reach the end point. If we assume that the acidity of the rain is due to the presence of sulfuric acid, what was the concentration of sulfuric acid in this sample of rain?
You are given a 1.50-g mixture of sodium nitrate and sodium chloride. You dissolve this mixture into 100 mL of water and then add an excess of 0.500 M silver nitrate solution. You produce a white solid, which you then collect, dry, and measure. The white solid has a mass of 0.641 g. a. If you had an extremely magnified view of the solution (to the atomic-molecular level), list the species you would see (include charges, if any). b. Write the balanced net ionic equation for the reaction that produces the solid. Include phases and charges. c. Calculate the percent sodium chloride in the original unknown mixture.
You wish to prepare 1 L of a 0.02-M potassium iodate solution. You require that the final concentration be within 1% of 0.02 M and that the concentration must be known accurately to the fourth decimal place. How would you prepare this solution? Specify the glassware you would use, the accuracy needed for the balance, and the ranges of acceptable masses of KIO3 that can be used.
A soft drink contains an unknown mass of citric acid, C3H5O(COOH)3. It requires 6.42 mL of 9.580 × 10−2-M NaOH to neutralize the citric acid in 10.0 mL of the soft drink. C3H5O(COOH)3(aq) + 3 NaOH(aq) → Na3C3H5O(COO)3(aq) + 3 H2O(ℓ) Determine which step in these calculations for the mass of citric acid in 1 mL soft drink is incorrect? Why? n (NaOH) = (6.42 mL)(1L/1000 mL)(9.580 × 10−2 mol/L) n (citric acid) = (6.15 × 10−4 mol NaOH) × (3 mol citric acid/1 mol NaOH) m (citric acid in sample) = (1.85 × 10−3 mol citric acid) × (192.12 g/mol citric acid) m (citric acid in 1 mL soft drink) = (0.354 g citric acid)/(10 mL soft drink) Determine the correct result.
You pour 150.0 mL of a 0.250 M lead(ll) nitrate solution into an empty 500-mL flask. What is the concentration of nitrate ions in the solution? What volume of 0.100 M sodium phosphate must be added to precipitate the lead(ll) ions from the solution?